Thallium(III) nitrate trihydrate

• Catalog No.: 163015
• CAS Number: 13453-38-8
• M. F.: H6N3O12Tl
• M. W.: 444.44384

SYNONYMS

• Title: 硝酸铊(III) 三水合物
• IUPAC name: thallium(3+) ion trihydrate trinitrate
• IUPAC Traditional name: thallium(3+) ion trihydrate trinitrate
• Synonyms: TTN; Thallium trinitrate

DATABASE IDS

• MDL Number: MFCD00149874
• CAS Number: 13453-38-8
• EC Number: 237-325-4
• PubChem SID: 24850018

PROPERTIES

• Linear Formula: Tl(NO3)3 · 3H2O
• Melting Point: 102-105 °C(lit.)
• GHS Signal Word: Danger
• GHS Hazard statements: H300-H330-H373-H411
• European Hazard Symbols: Highly toxic (T+)
• European Hazard Symbols: Nature polluting (N)
• GHS Precautionary statements: P260-P264-P273-P284-P301 + P310-P310
• RID/ADR: UN 2727 6.1/PG 2
• Risk Statements: 26/28-33-51/53
• Safety Statements: 13-28-45-61
• Hazard Class: 6.1
• UN Number: 2727
• Packing Group: 2
• German water hazard class: 2

DETAILS

Description (English)

Packaging
25, 100 g in glass bottle
Application
Reagent for the rapid oxidation of styrene derivatives to carbonyl compounds,1 for the regioselective ring expansion of cyclic aralkyl ketones via oxidative rearrangement,2 for the selective hydrolysis of thioacetals to carbonyl compounds3 and for a general synthetic method to 19-norsteroids.4 Mediates ring contraction of cyclic ketones to a series of trans-fused 10-methyl-2-decalones.5

Description (简体中文)

包装
25, 100 g in glass bottle
Application
本试剂可用于将苯乙烯衍生物快速氧化成羰基化合物，1用于通过氧化重排进行环芳烷基酮的区域选择性扩环反应，2用于硫缩醛到羰基化合物的选择性水解3以及用于 19-降甾族化合物的一般合成方法。4介导环酮的缩环反应，生成一系列反式稠合的 10-甲基-2-萘烷酮。5