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(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine_Molecular_structure_CAS_55700-44-2)
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(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine

Catalog No. 344109 Name Sigma Aldrich
CAS Number 55700-44-2 Website http://www.sigmaaldrich.com
M. F. C26H28FeNP Telephone 1-800-521-8956
M. W. 441.325981 Fax
Purity 95% Email
Storage Chembase ID: 147094

SYNONYMS

Title
(R)-(-)-N,N-二甲基-1-[(S)-2-(二苯基膦基)二茂铁基]乙胺
IUPAC name
λ2-iron(2+) ion 3-[(1R)-1-(dimethylamino)ethyl]-4-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide cyclopenta-2,4-dien-1-ide
IUPAC Traditional name
λ2-iron(2+) ion 3-[(1R)-1-(dimethylamino)ethyl]-4-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide cyclopentadienide

DATABASE IDS

PubChem SID 24861224
MDL Number MFCD00075286
CAS Number 55700-44-2

PROPERTIES

Empirical Formula (Hill Notation) C26H28FeNP
Purity 95%
Melting Point 141-143 °C(lit.)
Optical Rotation [α]20/D -355°, c = 0.6 in ethanol
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H302-H312-H315-H319-H332-H335
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P280-P305 + P351 + P338
Risk Statements 20/21/22-36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Packaging
100 mg in glass bottle
Application
Ligand used in the enantioselective vinylation of aldehydes.1
Description (简体中文)
包装
100 mg in glass bottle
Application
醛的不对称乙烯化反应的配体。1

REFERENCES