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(R)-(+)-N,N-Dimethyl-1-ferrocenylethylamine_Molecular_structure_CAS_31886-58-5)
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(R)-(+)-N,N-Dimethyl-1-ferrocenylethylamine

Catalog No. 344125 Name Sigma Aldrich
CAS Number 31886-58-5 Website http://www.sigmaaldrich.com
M. F. C14H19FeN Telephone 1-800-521-8956
M. W. 257.15236 Fax
Purity 97% Email
Storage Chembase ID: 147091

SYNONYMS

Title
(R)-(+)-N,N-二甲基-1-二茂铁基乙胺
IUPAC name
λ2-iron(2+) ion 3-[(1R)-1-(dimethylamino)ethyl]cyclopenta-2,4-dien-1-ide cyclopenta-2,4-dien-1-ide
IUPAC Traditional name
λ2-iron(2+) ion 3-[(1R)-1-(dimethylamino)ethyl]cyclopenta-2,4-dien-1-ide cyclopentadienide
Synonyms
(R)-(+)-[1-(Dimethylamino)ethyl]ferrocene
(R)-(+)-[1-(二甲氨基)乙基]二茂铁

DATABASE IDS

CAS Number 31886-58-5
PubChem SID 24861227
MDL Number MFCD00066273

PROPERTIES

Empirical Formula (Hill Notation) C14H19FeN
Purity 97%
Boiling Point 120-121 °C/0.7 mmHg(lit.)
Density 1.222 g/mL at 20 °C(lit.)
Flash Point 113 °C
Flash Point 235.4 °F
Optical Rotation [α]20/D +13°, c = 1 in ethanol (5 h)
Refractive Index n20/D 1.589(lit.)
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P305 + P351 + P338
Risk Statements 36/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Application
Ligand used in the preparation of chiral allylic alcohols,1 axially chiral allenecarboxylic esters,2 and rhodium(I)-catalyzed asymmetric hydrosilylation of ketones.3
Packaging
100, 500 mg in ampule
Description (简体中文)
Application
用于手性烯丙醇、1轴向手性丙二烯羧酸酯的制备2,以及酮的铑(I)催化不对称氢化硅烷化反应的配体。3
包装
100, 500 mg in ampule

REFERENCES