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Chloroborane methyl sulfide complex

Catalog No. 298441 Name Sigma Aldrich
CAS Number 63348-81-2 Website http://www.sigmaaldrich.com
M. F. C2H7BClS Telephone 1-800-521-8956
M. W. 109.40598 Fax
Purity Email
Storage Chembase ID: 147087

SYNONYMS

Title
单氯硼烷二甲基硫醚络合物
IUPAC name
chloro(dimethyl-λ4-sulfanylidene)borane
IUPAC Traditional name
chloro(dimethyl-λ4-sulfanylidene)borane
Synonyms
monoChloroborane methyl sulfide complex
硫化氯硼烷甲基络合物
Boron monochloride methyl sulfide complex
Chloro(dimethyl sulfide)dihydroboron
Monochloroborane-dimethyl sulfide

DATABASE IDS

CAS Number 63348-81-2
MDL Number MFCD00013210
PubChem SID 24857987

PROPERTIES

Linear Formula (CH3)2S·BH2Cl
Density 1.059 g/mL at 25 °C(lit.)
Flash Point 24 °C
Flash Point 75.2 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H226-H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 2920 8/PG 2
Risk Statements 10-14-34
Safety Statements 16-26-27-36/37/39-45
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 8
UN Number 2920
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Packaging
50 g in Sure/Seal™
Application
Reactant for:
• Substitution reactions1
• Boronation reactions2
• Preparation of diborylamines3
• Preparation of unsymmetrical borafluorenes via low-temperature carbon-hydrogen activation reactions4
• Asymmetrical aldol reactions with a-chiral aldehydes5
• Addition reaction with α-pinene6
Reagent for hydroboration and synthesis of chlorodialkylboranes.
Description (简体中文)
包装
50 g in Sure/Seal™
Application
Reactant for:
• Substitution reactions1
• Boronation reactions2
• Preparation of diborylamines3
• Preparation of unsymmetrical borafluorenes via low-temperature carbon-hydrogen activation reactions4
• Asymmetrical aldol reactions with a-chiral aldehydes5
• Addition reaction with α-pinene6
用于硼氢化反应和合成氯二烷基硼烷的试剂。

REFERENCES