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Boron trifluoride methyl etherate_Molecular_structure_CAS_353-42-4)
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Boron trifluoride methyl etherate

Catalog No. 218847 Name Sigma Aldrich
CAS Number 353-42-4 Website http://www.sigmaaldrich.com
M. F. C2H6BF3O Telephone 1-800-521-8956
M. W. 113.8746496 Fax
Purity Email
Storage Chembase ID: 147086

SYNONYMS

Title
三氟化硼二甲醚
IUPAC name
(dimethyloxo)trifluoro-λ5-borane
IUPAC Traditional name
(dimethyloxo)trifluoro-λ5-borane
Synonyms
(Dimethyl ether)trifluoroboron

DATABASE IDS

EC Number 206-532-1
CAS Number 353-42-4
MDL Number MFCD00013192
PubChem SID 24853093
Beilstein Number 3613739

PROPERTIES

Linear Formula BF3 · O(CH3)2
Auto Ignition Point 455 °F
Boiling Point 126-127 °C(lit.)
Density 1.239 g/mL at 25 °C(lit.)
Flash Point 62 °C
Flash Point 143.6 °F
Melting Point -15 °C(lit.)
Refractive Index n20/D 1.308(lit.)
Explode Limits 21.6 %
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H260-H314
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P223-P231 + P232-P280-P305 + P351 + P338-P370 + P378-P422
RID/ADR UN 2965 4.3/PG 1
Risk Statements 14/15-34
RTECS ED8400000
Safety Statements 16-26-28-36/37/39-45
Hazard Class 4.3
UN Number 2965
Packing Group 1
German water hazard class 3

DETAILS

Description (English)
Packaging
50 g in glass bottle
Application
Reactant or reagent involved in:
• Deconvoluting the chemical reaction kinetics of platinum-silver ligand exchange1
• Synthesis of neurogenic ganglioside LLG-3 from starfish via glycosylation reactions2
• Synthesis of peloruside via lactonization and relay ring-closing metathesis cyclization3
• FRET for monitoring Pd-catalyzed nucleophilic allylic substitution reactions4
• Single molecuel imaging of fluorophore-tagged palldium(II) complexes5
• β-elimination and rearrangement reactions for synthesis of exocyclic vinyl ethers6
Description (简体中文)
包装
50 g in glass bottle
Application
Reactant or reagent involved in:
• Deconvoluting the chemical reaction kinetics of platinum-silver ligand exchange1
• Synthesis of neurogenic ganglioside LLG-3 from starfish via glycosylation reactions2
• Synthesis of peloruside via lactonization and relay ring-closing metathesis cyclization3
• FRET for monitoring Pd-catalyzed nucleophilic allylic substitution reactions4
• Single molecuel imaging of fluorophore-tagged palldium(II) complexes5
• β-elimination and rearrangement reactions for synthesis of exocyclic vinyl ethers6

REFERENCES