[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane

• Catalog No.: 379670
• CAS Number: 95464-05-4
• M. F.: C35H30Cl4FeP2Pd
• M. W.: 816.637222

SYNONYMS

• Title: [1,1′-双(二苯基膦)二茂铁]二氯化钯(II)二氯甲烷络合物
• IUPAC name: λ^2-iron(2+) ion bis(3-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide) dichloromethane dichloropalladium
• IUPAC Traditional name: λ^2-iron(2+) ion bis(3-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide) methylene chloride palladium chloride
• Synonyms: Pd(dppf)Cl2 · CH2Cl2; [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (1:1); Pd(dppf)Cl2 · DCM

DATABASE IDS

• CAS Number: 95464-05-4
• PubChem SID: 24863679
• MDL Number: MFCD00792899

PROPERTIES

• Empirical Formula (Hill Notation): C35H30Cl4FeP2Pd
• Melting Point: 275-280 °C
• GHS Signal Word: Warning
• GHS Hazard statements: H302-H312-H315-H319-H332-H335-H351
• European Hazard Symbols: Harmful (Xn)
• GHS Precautionary statements: P261-P280-P305 + P351 + P338
• Risk Statements: 20/21/22-36/37/38-40
• Safety Statements: 26-36/37
• German water hazard class: 3

DETAILS

Description (English)

Analysis Note
Catalyst employed in the borylation of aryl halides with Bis(pinacolato)diboron(473294) as well as the coupling of the derived arylboronic esters with aryl halides leading to biaryls.1 Also used in the synthesis of lactams by CO insertion2 and medium-ring aryl ethers by intramolecular coupling of an aryl halide with an alcohol.3
Packaging
1, 5, 25 g in glass bottle
Application
Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Description (简体中文)

Analysis Note
催化剂，用于芳基卤化物和双(频哪醇合)二硼 (473294) 的硼化反应，以及芳基硼酯衍生物和芳基卤化物偶联生成联芳基化合物的反应。1也可用于 CO 插入反应合成内酰胺2以及芳基卤化物和醇的分子内偶联反应合成中环芳基醚。3
包装
1, 5, 25 g in glass bottle
Application
Application Guide for Palladium Catalyzed Cross-Coupling Reactions