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Ferrocene

Catalog No. F408 Name Sigma Aldrich
CAS Number 102-54-5 Website http://www.sigmaaldrich.com
M. F. C10H10Fe Telephone 1-800-521-8956
M. W. 186.0314 Fax
Purity 98% Email
Storage Chembase ID: 127413

SYNONYMS

Title
二茂铁
IUPAC name
λ2-iron(2+) ion bis(cyclopenta-2,4-dien-1-ide)
IUPAC Traditional name
λ2-iron(2+) ion bis(cyclopentadienide)
Synonyms
双环戊二烯基铁
Bis(cyclopentadienyl)iron
二环戊二烯铁
Di(cyclopentadienyl)iron

DATABASE IDS

PubChem SID 24894802
EC Number 203-039-3
CAS Number 102-54-5
MDL Number MFCD00001427

PROPERTIES

Linear Formula Fe(C5H5)2
Purity 98%
Absorption Wavelength λmax 358 nm
Boiling Point 249 °C(lit.)
Melting Point 172-174 °C(lit.)
Vapor Pressure 0.03 mmHg ( 40 °C)
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H228-H302
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P210
RID/ADR UN 1325 4.1/PG 2
Risk Statements 11-22
RTECS LK0700000
Hazard Class 4.1
UN Number 1325
Packing Group 2
German water hazard class 2

DETAILS

Description (English)
Application
Synthetic reagent used as as a source of useful ferrocene derivatives, including most substituted ferrocenes and precursor of substituted cyclopentadienes and cyclopentanes; the derived ferrocenium salts find use as mild oxidants; replacement of one ring by arenes yields cationic complexes which undergo nucleophilic addition and substitution at the arene ring, leading to substituted arenes.
Packaging
5, 100, 500 g in glass bottle
Description (简体中文)
Application
Synthetic reagent used as as a source of useful ferrocene derivatives, including most substituted ferrocenes and precursor of substituted cyclopentadienes and cyclopentanes; the derived ferrocenium salts find use as mild oxidants; replacement of one ring by arenes yields cationic complexes which undergo nucleophilic addition and substitution at the arene ring, leading to substituted arenes.
包装
5, 100, 500 g in glass bottle

REFERENCES