Home > Compound List > Product Information
Borane dimethyl sulfide complex solution_Molecular_structure_CAS_13292-87-0)
Click picture or here to close

Borane dimethyl sulfide complex solution

Catalog No. 192120 Name Sigma Aldrich
CAS Number 13292-87-0 Website http://www.sigmaaldrich.com
M. F. C2H9BS Telephone 1-800-521-8956
M. W. 75.96886 Fax
Purity Email
Storage Chembase ID: 139969

SYNONYMS

Title
硼烷二甲基硫醚络合物 溶液
IUPAC name
(methylsulfanyl)methane borane
IUPAC Traditional name
dimethyl sulfide borane
Synonyms
BMS
Trihydro[thiobis[methane]]boron

DATABASE IDS

PubChem SID 24851530
Beilstein Number 3663489
MDL Number MFCD00013189
CAS Number 13292-87-0

PROPERTIES

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P223-P231 + P232-P261-P370 + P378-P422
RID/ADR UN 3399 4.3/PG 1
Risk Statements 11-14/15-19-37-41
Safety Statements 16-26-39-43
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H260-H315-H318-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Storage Temperature 2-8°C
Supplemental Hazard Statements May form explosive peroxides., Reacts violently with water.
Hazard Class 4.3
UN Number 3399
Packing Group 1
German water hazard class 3
Concentration 2.0 M in THF
Linear Formula (CH3)2S · BH3
Density 0.855 g/mL at 25 °C
Flash Point -17 °C
Flash Point 1.4 °F

DETAILS

Description (English)
Application
Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.6 CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to chiral 1,3-diols.7 Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.8
Reactant used as a regioselective reducing agent1,2Reactant involved in:
• Hydroboration / oxidation3,4Synthesis of cage compounds5
Packaging
100, 800 mL in Sure/Seal™
Description (简体中文)
Application
与树枝状聚合物负载的 L-吡咯烷醇共同用于茚酮和四氢萘酮的不对称还原反应。6二茂铁基-1,3-二酮转化为手性 1,3-二醇的 CBS 催化不对称还原反应。7C3-对称三脚羟基酰胺催化的酮高度不对称还原反应。8
Reactant used as a regioselective reducing agent1,2Reactant involved in:
• Hydroboration / oxidation3,4Synthesis of cage compounds5
包装
100, 800 mL in Sure/Seal™

REFERENCES