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3-Butenylmagnesium bromide solution_Molecular_structure_CAS_7103-09-5)
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3-Butenylmagnesium bromide solution

Catalog No. 419591 Name Sigma Aldrich
CAS Number 7103-09-5 Website http://www.sigmaaldrich.com
M. F. C4H7BrMg Telephone 1-800-521-8956
M. W. 159.30738 Fax
Purity Email
Storage Chembase ID: 146708

SYNONYMS

Title
3-丁烯基溴化镁 溶液
IUPAC name
bromo(but-3-en-1-yl)magnesium
IUPAC Traditional name
bromo(but-3-en-1-yl)magnesium

DATABASE IDS

PubChem SID 24866263
MDL Number MFCD00209554
CAS Number 7103-09-5

PROPERTIES

Concentration 0.5 M in THF
Linear Formula H2C=CHCH2CH2MgBr
Boiling Point 65 °C
Density 0.937 g/mL at 25 °C
Flash Point -30 °C
Flash Point -22 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H260-H314-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
GHS Precautionary statements P210-P223-P231 + P232-P261-P370 + P378-P422
RID/ADR UN 3399 4.3/PG 1
Risk Statements 11-14/15-19-36/37/38
Safety Statements 16-26-43
Supplemental Hazard Statements May form explosive peroxides., Reacts violently with water.
Hazard Class 4.3
UN Number 3399
Packing Group 1
German water hazard class 3

DETAILS

Description (English)
Application
Synthetic building block that can undergo ring-formation reactions facilitated by ruthenium catalysts.
Used in a key diastereoselective step in the synthesis of (-)-muricatacin from L-tartaric acid.1
Packaging
100, 800 mL in Sure/Seal™
Description (简体中文)
Application
可参与钌催化剂协助的环化反应的合成结构单元。
用于由 L-酒石酸合成 (-)-muricatacin 的非对映选择性关键步骤。1
包装
100, 800 mL in Sure/Seal™

REFERENCES