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(R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol_Molecular_structure_CAS_14347-78-5)
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(R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol

Catalog No. 241806 Name Sigma Aldrich
CAS Number 14347-78-5 Website http://www.sigmaaldrich.com
M. F. C6H12O3 Telephone 1-800-521-8956
M. W. 132.15768 Fax
Purity 98% Email
Storage Chembase ID: 118994

SYNONYMS

Title
(R)-(-)-甘油醇缩丙酮
IUPAC name
[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]methanol
IUPAC Traditional name
[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]methanol
Synonyms
L-2,3-O-isopropylidene-sn-glycerol
2,3-异亚丙基-sn-甘油
2,3-Isopropylidene-sn-glycerol
L-α,β-Isopropylideneglycerol
L-α,β-异亚丙基甘油
L-2,3-O-异亚丙基-sn-甘油

DATABASE IDS

PubChem SID 24854331
Beilstein Number 80117
CAS Number 14347-78-5
MDL Number MFCD00003213

PROPERTIES

Empirical Formula (Hill Notation) C6H12O3
Optical Purity ee: 99% (GLC)
Purity 98%
Boiling Point 72-73 °C/8 mmHg(lit.)
Density 1.062 g/mL at 25 °C(lit.)
Flash Point 79 °C
Flash Point 174.2 °F
Optical Rotation [α]20/D -13.7°, neat
Refractive Index n20/D 1.434(lit.)
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Storage Temperature 2-8°C
German water hazard class 3

DETAILS

Description (English)
Application
Both (R)- and (S)-forms are chiral synthons used in the preparation of tetraoxaspiroundecanes,1 diglycerides,2 and glyceryl phosphates.3
Used in a new, efficient route to spiropyrans.
Packaging
1, 5 g in glass bottle
Description (简体中文)
Application
(R)- 和 (S)-型均为手性合成子,用于制备四氧杂螺十一烷、1二甘油酯2和甘油磷酸酯。3
用于螺吡喃的新型、高效合成路线。
包装
1, 5 g in glass bottle

REFERENCES