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2-Methyl-1-propenylmagnesium bromide solution_Molecular_structure_CAS_38614-36-7)
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2-Methyl-1-propenylmagnesium bromide solution

Catalog No. 419613 Name Sigma Aldrich
CAS Number 38614-36-7 Website http://www.sigmaaldrich.com
M. F. C4H7BrMg Telephone 1-800-521-8956
M. W. 159.30738 Fax
Purity Email
Storage Chembase ID: 146664

SYNONYMS

Title
2-甲基-1-丙烯基溴化镁 溶液
IUPAC name
bromo(2-methylprop-1-en-1-yl)magnesium
IUPAC Traditional name
bromo(2-methylprop-1-en-1-yl)magnesium

DATABASE IDS

PubChem SID 24866265
CAS Number 38614-36-7
MDL Number MFCD00209600

PROPERTIES

Concentration 0.5 M in THF
Linear Formula (CH3)2C=CHMgBr
Density 0.952 g/mL at 25 °C
Flash Point -15 °C
Flash Point 5 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H261-H314-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P231 + P232-P261-P280-P305 + P351 + P338-P422
RID/ADR UN 3399 4.3/PG 2
Risk Statements 11-14/15-19-34-37
Safety Statements 16-26-36/37/39-43-45
Supplemental Hazard Statements May form explosive peroxides., Reacts violently with water.
Hazard Class 4.3
UN Number 3399
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Application
Used in a study of a palladium-catalyzed coupling with aryl tosylates.
Used in a synthesis of (2S,3S)-3′-fluoroisoleucine.1
Packaging
100, 800 mL in Sure/Seal™
Description (简体中文)
Application
用于合成 (2S,3S)-3′-氟代异亮氨酸。1
用于研究与芳基甲苯磺酸酯的钯催化偶联反应。
包装
100, 800 mL in Sure/Seal™

REFERENCES