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Triethylborane solution_Molecular_structure_CAS_97-94-9)
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Triethylborane solution

Catalog No. 179701 Name Sigma Aldrich
CAS Number 97-94-9 Website http://www.sigmaaldrich.com
M. F. C6H15B Telephone 1-800-521-8956
M. W. 97.9943 Fax
Purity Email
Storage Chembase ID: 129989

SYNONYMS

Title
三乙基硼 溶液
IUPAC name
triethylborane
IUPAC Traditional name
triethylborane

DATABASE IDS

MDL Number MFCD00009022
Beilstein Number 1731462
CAS Number 97-94-9
PubChem SID 24850826

PROPERTIES

Concentration 1.0 M in THF
Linear Formula (C2H5)3B
Density 0.865 g/mL at 25 °C
Flash Point -17 °C
Flash Point 1.4 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H250-H261-H314-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P222-P231 + P232-P261-P280-P422
RID/ADR UN 3399 4.3/PG 2
Risk Statements 11-19-34-37
Safety Statements 16-26-36/37/39-45
Supplemental Hazard Statements May form explosive peroxides.
Hazard Class 4.3
UN Number 3399
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Packaging
100, 800 mL in Sure/Seal™
Application
Catalyst for:
• Allylation of aldehydes1
• Decarboxylative C-C bond cleavage reactions2
• Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations3
• Regioselective hydroxyalkylation of unsaturated oxime ethers4Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes5Reactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential6
Description (简体中文)
包装
100, 800 mL in Sure/Seal™
Application
Catalyst for:
• Allylation of aldehydes1
• Decarboxylative C-C bond cleavage reactions2
• Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations3
• Regioselective hydroxyalkylation of unsaturated oxime ethers4Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes5Reactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential6

REFERENCES