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R-Alpine-Borane® solution_Molecular_structure_CAS_73624-47-2)
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R-Alpine-Borane® solution

Catalog No. 232734 Name Sigma Aldrich
CAS Number 73624-47-2 Website http://www.sigmaaldrich.com
M. F. C18H31B Telephone 1-800-521-8956
M. W. 258.24974 Fax
Purity Email
Storage Chembase ID: 137129

SYNONYMS

Title
R-Alpine-Borane® 溶液
IUPAC name
(1s,5s)-9-[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl]-9-borabicyclo[3.3.1]nonane
IUPAC Traditional name
(1s,5s)-9-[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl]-9-borabicyclo[3.3.1]nonane
Synonyms
B-Isopinocampheyl-9-borabicyclo[3.3.1]nonane solution
B-异松蒎基-9-硼二环[3.3.1]壬烷 溶液

DATABASE IDS

MDL Number MFCD00074776
CAS Number 73624-47-2
PubChem SID 24853817

PROPERTIES

Concentration 0.5 M in THF
Empirical Formula (Hill Notation) C18H31B
Density 0.896 g/mL at 25 °C
Flash Point -17 °C
Flash Point 1.4 °F
Optical Rotation [α]20/D -3.0°, neat
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H315-H319-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
GHS Precautionary statements P210-P261-P305 + P351 + P338
RID/ADR UN 1993 3/PG 2
Risk Statements 11-19-36/37
Safety Statements 16-26
Supplemental Hazard Statements May form explosive peroxides.
Hazard Class 3
UN Number 1993
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Packaging
100 mL in Sure/Seal™
Application
R- and S-Alpine-Boranes are used for asymmetric reduction of aldehydes1,2 and prochiral ketones.3,4,2
Legal Information
Alpine-Borane is a registered trademark of Sigma-Aldrich Co. LLC
Description (简体中文)
包装
100, 800 mL in Sure/Seal™
Application
R- 和 S-Alpine-Boranes 用于醛1,2和前手性酮的不对称还原反应。3,4,2
法律信息
Alpine-Borane 注册商标 Sigma-Aldrich Co. LLC

REFERENCES