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Oxalyl bromide_Molecular_structure_CAS_15219-34-8)
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Oxalyl bromide

Catalog No. 113034 Name Sigma Aldrich
CAS Number 15219-34-8 Website http://www.sigmaaldrich.com
M. F. C2Br2O2 Telephone 1-800-521-8956
M. W. 215.8282 Fax
Purity 97% Email
Storage Chembase ID: 146509

SYNONYMS

Title
草酰溴
IUPAC name
oxalic dibromide
IUPAC Traditional name
oxalic dibromide
Synonyms
Ethanedioyl dibromide
NSC 96957

DATABASE IDS

PubChem SID 24847129
MDL Number MFCD00000113
CAS Number 15219-34-8
EC Number 239-271-7
Beilstein Number 1744437

PROPERTIES

Linear Formula BrCOCOBr
Purity 97%
Boiling Point 16-17 °C/10 mmHg(lit.)
Melting Point -19 °C(lit.)
Refractive Index n20/D 1.522(lit.)
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H314-H332
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 2922 8/PG 1
Risk Statements 14-20-29-34
Safety Statements 26-36/37/39-45
Storage Temperature 2-8°C
Supplemental Hazard Statements Contact with water liberates toxic gas., Reacts violently with water.
Hazard Class 8
UN Number 2922
Packing Group 1
German water hazard class 3

DETAILS

Description (English)
Application
Converts cyclopentane-1,3-dione to 3-bromocyclopenten-2-one.7
Used in synthetic applications of carbon-substituted iminium salts1Reactant for:
• Synthesis of mutasynthons added to cultures of A. pretiosum for mutasynthetic generation of ansamitocin derivatives2
• Oxalic acid formation from hydroxyl radical substitutions3
• Cyclization to produce CRF1 receptor antagonists4
• Preparation, optical and electrochemical studies of thiophene end capped olig(2,3-alkylthieno[3,4-b]pyrazine)5
• Asymmetrical synthesis of glycosyl chlorides and bromides6
Packaging
25, 100 g in glass bottle
Description (简体中文)
Application
将环戊烷-1,3-二酮转化为 3-溴环戊烯-2-酮。7
Used in synthetic applications of carbon-substituted iminium salts1Reactant for:
• Synthesis of mutasynthons added to cultures of A. pretiosum for mutasynthetic generation of ansamitocin derivatives2
• Oxalic acid formation from hydroxyl radical substitutions3
• Cyclization to produce CRF1 receptor antagonists4
• Preparation, optical and electrochemical studies of thiophene end capped olig(2,3-alkylthieno[3,4-b]pyrazine)5
• Asymmetrical synthesis of glycosyl chlorides and bromides6
包装
25, 100 g in glass bottle

REFERENCES