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Lithium aluminum hydride solution_Molecular_structure_CAS_16853-85-3)
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Lithium aluminum hydride solution

Catalog No. 212792 Name Sigma Aldrich
CAS Number 16853-85-3 Website http://www.sigmaaldrich.com
M. F. AlLi Telephone 1-800-521-8956
M. W. 33.922538 Fax
Purity Email
Storage Chembase ID: 108633

SYNONYMS

Title
氢化铝锂 溶液
IUPAC name
lithium(1+) ion alumanuide
IUPAC Traditional name
lithium(1+) ion alumanuide
Synonyms
LAH
Lithium alanate
Lithium tetrahydroaluminate

DATABASE IDS

MDL Number MFCD00011075
PubChem SID 24852742
CAS Number 16853-85-3

PROPERTIES

Concentration 1.0 M in diethyl ether
Linear Formula LiAlH4
Density 0.716 g/mL at 25 °C
Flash Point -17 °C
Flash Point 1.4 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H224-H302-H315-H318-H336
European Hazard Symbols Highly flammable Highly flammable (F+)
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
GHS Precautionary statements P210-P261-P280-P305 + P351 + P338
RID/ADR UN 1411 4.3/PG 1
Risk Statements 12-19-22-36/38-66-67
Safety Statements 16-26
Supplemental Hazard Statements May form explosive peroxides., Repeated exposure may cause skin dryness or cracking.
Hazard Class 4.3
UN Number 1411
Packing Group 1
German water hazard class 1

DETAILS

Description (English)
Packaging
100, 800 mL in Sure/Seal™
Application
Reactant or reagent for:
• The preparation of thermoplastic polyester polyamides from oleic acid1
• Lithium-polymer batteries2
• Hydrodefluorination of gem-difluoromethylene derivatives3
• Asymmetric aldol reactions4
• Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties5LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols6
Description (简体中文)
包装
100, 800 mL in Sure/Seal™
Application
Reactant or reagent for:
• The preparation of thermoplastic polyester polyamides from oleic acid1
• Lithium-polymer batteries2
• Hydrodefluorination of gem-difluoromethylene derivatives3
• Asymmetric aldol reactions4
• Synthesis of Li-Al-N-H composites with hydrogen absorption / desorption properties5LAH is a powerful reducing agent for many different reduction reactions such as that of ketones to alcohols6

REFERENCES