(1S,2S,3R,5S)-(+)-Pinanediol

• Catalog No.: 282367
• CAS Number: 18680-27-8
• M. F.: C10H18O2
• M. W.: 170.24872
• Purity: 99%

SYNONYMS

• Title: (1S,2S,3R,5S)-(+)-蒎烷二醇
• IUPAC name: (1S,2S,3R,5S)-2,6,6-trimethylbicyclo[3.1.1]heptane-2,3-diol
• IUPAC Traditional name: (1S,2S,3R,5S)-2,6,6-trimethylbicyclo[3.1.1]heptane-2,3-diol
• Synonyms: (1S,2S,3R,5S)-2,3-蒎烷二醇; [1S-(1α,2α,3α,5α)]-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇; (+)-2-羟基异松蒎醇; [1S-(1α,2α,3α,5α)]-2,6,6-Trimethylbicyclo[3.1.1]heptane-2,3-diol; (+)-2-Hydroxyisopinocampheol; (1S,2S,3R,5S)-2,3-Pinanediol; (1S,2S,3R,5S)-2,6,6-Trimethylbicyclo[3.1.1]heptane-2,3-diol; (1S,2S,3R,5S)-2,6,6-三甲基二环[3.1.1]庚-2,3-二醇

DATABASE IDS

• PubChem SID: 24857043
• CAS Number: 18680-27-8
• MDL Number: MFCD00077851
• Beilstein Number: 1853591

PROPERTIES

• Empirical Formula (Hill Notation): C10H18O2
• Optical Purity: ee: 99% (GLC)
• Purity: 99%
• Flash Point: >113 °C
• Flash Point: >235.4 °F
• Melting Point: 57-59 °C(lit.)
• Optical Rotation: [α]20/D +8.5°, c = 6.5 in toluene
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1 kg in glass bottle
1, 5, 100 g in glass bottle
Application
Chiral reagent in the synthesis of homochiral α-hydroxyketones1 and in the resolution of prolineboronate esters.2
Precursor to a chiral allyl boronate used in a preparation of chiral β-hydroxyallylsilanes.

Description (简体中文)

包装
1 kg in glass bottle
1, 5, 100 g in glass bottle
Application
手性烯丙基硼酸酯（用于制备手性 β-羟基烯丙基硅烷）的前体。
用于合成纯手性 α-羟基酮1以及拆分脯氨酸硼酸酯的手性试剂。2