(1R)-(-)-Menthyl chloroformate

• Catalog No.: 245305
• CAS Number: 14602-86-9
• M. F.: C11H19ClO2
• M. W.: 218.72036

SYNONYMS

• Title: (1R)-(-)-氯甲酸薄荷酯
• IUPAC name: (1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl chloroformate
• IUPAC Traditional name: (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl chloroformate
• Synonyms: (-)-氯甲酸薄荷酯; (-)-Menthyl chloroformate

DATABASE IDS

• PubChem SID: 24854513
• Beilstein Number: 2414686
• MDL Number: MFCD00009694
• CAS Number: 14602-86-9

PROPERTIES

• Empirical Formula (Hill Notation): C11H19ClO2
• Optical Purity: ee: 99% (GLC)
• Boiling Point: 108-109 °C/11 mmHg(lit.)
• Density: 1.02 g/mL at 25 °C(lit.)
• Flash Point: 70 °C
• Flash Point: 158 °F
• Optical Rotation: [α]20/D -83°, c = 1 in chloroform
• Refractive Index: n20/D 1.458(lit.)
• Vapor Pressure: 0.01 psi ( 20 °C)
• GHS Signal Word: Danger
• GHS Hazard statements: H314-H331
• European Hazard Symbols: Toxic (T)
• European Hazard Symbols: Nature polluting (N)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P261-P280-P305 + P351 + P338-P310
• RID/ADR: UN 3277 6.1/PG 2
• Risk Statements: 23-34-51/53
• Safety Statements: 26-36/37/39-45-61
• Storage Temperature: 2-8°C
• Hazard Class: 6.1
• UN Number: 3277
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Packaging
25, 100 g in glass bottle
Application
Chiral derivatizing agent used for the resolution of alcohols and amines by GC, HPLC, or crystallization.1
Readily forms a chloroimidodicarbonate which asymmetrically chlorinates silyl enol ethers under mild conditions and in good yields.

Description (简体中文)

包装
25, 100 g in glass bottle
Application
易于形成氯亚氨重碳酸盐，可在温和条件下不对称氯化硅基烯醇醚并且产量高。
用于通过 GC、HPLC 或结晶作用来拆分醇类和胺类的手性衍生试剂。1