(3aR-cis)-(+)-3,3a,8,8a-Tetrahydro-2H-indeno[1,2-d]oxazol-2-one

• Catalog No.: 463965
• CAS Number: 135969-65-2
• M. F.: C10H9NO2
• M. W.: 175.18396
• Purity: 97%

SYNONYMS

• Title: (3aR-顺)-(+)-3,3a,8,8a-四氢-2H-茚并[1,2-d]噁唑-2-酮
• IUPAC name: (3aR,8aS)-2H,3H,3aH,8H,8aH-indeno[1,2-d][1,3]oxazol-2-one
• IUPAC Traditional name: (3aR,8aS)-3H,3aH,8H,8aH-indeno[1,2-d][1,3]oxazol-2-one

DATABASE IDS

• MDL Number: MFCD00674088
• CAS Number: 135969-65-2
• PubChem SID: 24870124

PROPERTIES

• Empirical Formula (Hill Notation): C10H9NO2
• Optical Purity: ee: 99% (HPLC)
• Purity: 97%
• Melting Point: 203-209 °C(lit.)
• Optical Rotation: [α]22/D +76°, c = 0.65 in ethyl acetate
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Application
Versatile chiral auxiliary used in a variety of highly diastereoselective reactions such as Michael additions,1 Diels-Alder reactions,2 cyclopropanations,3 and allylations.4
Packaging
1, 5 g in glass bottle

Description (简体中文)

Application
多功能手性助剂，用于各种高非对映选择性反应，例如 Michael 加成反应、1Diels-Alder 反应、2环丙烷化反应3和烯丙基化反应。4
包装
1, 5 g in glass bottle