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Palladium(II) trifluoroacetate

Catalog No. 299685 Name Sigma Aldrich
CAS Number 42196-31-6 Website http://www.sigmaaldrich.com
M. F. C4F6O4Pd Telephone 1-800-521-8956
M. W. 332.4508192 Fax
Purity 97% Email
Storage Chembase ID: 98341

SYNONYMS

Title
三氟乙酸钯(II)
IUPAC name
[(trifluoroacetyl)oxy]palladio 2,2,2-trifluoroacetate
IUPAC Traditional name
[(trifluoroacetyl)oxy]palladio 2,2,2-trifluoroacetate
Synonyms
三氟乙酸 钯(II) 盐
Trifluoroacetic acid palladium(II) salt
Pd(TFA)2

DATABASE IDS

PubChem SID 24858054
MDL Number MFCD00013204
CAS Number 42196-31-6

PROPERTIES

Linear Formula (CF3COO)2Pd
Purity 97%
Apperance solid
Melting Point ~220 °C
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-37/39
German water hazard class 3

DETAILS

Description (English)
Application
Catalyst used for the mild decarboxylation of electron-rich aromatic acids1 and the direct cross-coupling of unactivated arenes.2
Catalyzes the selective allylic oxidation of geranylacetone and other olefins to their allyl acetates, which can then be converted to keto alcohols.
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Packaging
1, 5 g in glass bottle
Description (简体中文)
Application
可催化香叶基丙酮和其他烯烃的选择性烯丙基氧化,生成相应的乙酸丙烯酯,而后可转化成酮醇。
用于富电子芳酸的温和脱羧反应1以及未活化芳烃的直接交叉偶联反应的催化剂。2
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
包装
1, 5 g in glass bottle

REFERENCES