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Cesium fluoride_Molecular_structure_CAS_13400-13-0)
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Cesium fluoride

Catalog No. 255718 Name Sigma Aldrich
CAS Number 13400-13-0 Website http://www.sigmaaldrich.com
M. F. CsF Telephone 1-800-521-8956
M. W. 151.9038532 Fax
Purity 99.99% trace metals basis Email
Storage Chembase ID: 94327

SYNONYMS

Title
氟化铯
IUPAC name
caesium(1+) ion fluoride
IUPAC Traditional name
caesium(1+) ion fluoride
Synonyms
NSC 84270

DATABASE IDS

MDL Number MFCD00010960
CAS Number 13400-13-0
EC Number 236-487-3
PubChem SID 24855475

PROPERTIES

Empirical Formula (Hill Notation) CsF
Purity 99.99% trace metals basis
Apperance solid
Density 4.115 g/mL at 25 °C(lit.)
Melting Point 682 °C(lit.)
Solubility methanol: slightly soluble
Solubility pyridine: insoluble
GHS Pictograms GHS05
GHS Pictograms GHS06
GHS Signal Word Danger
GHS Hazard statements H301 + H311 + H331-H314
European Hazard Symbols Toxic Toxic (T)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P261-P280-P301 + P310-P305 + P351 + P338-P310
RID/ADR UN 2923 8/PG 2
Risk Statements 23/24/25-34
RTECS FK9650000
Safety Statements 26-36/37/39-45
Hazard Class 8
UN Number 2923
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Application
Used as a base in the Suzuki carbonylative coupling of enol triflates with vinyl boronic acids.5
Reactant for:
• Preparation of building blocks for synthesis of fluoroallylic compounds1
• Synthesis of alcohols via hydrolysis of alkyl silyl ethers at neutral pH in buffered mixed organic-aqueous solutions2
• Nucleophilic fluorination of alkynyliodonium salts to form fluorovinylic compounds3
• Nucleophilic aromatic substitution (SNAr) reactions4
Packaging
10, 50 g in poly bottle
Description (简体中文)
Application
用作烯醇三氟甲磺酸酯与乙烯基硼酸进行羰化 Suzuki 偶联中的碱。5
Reactant for:
• Preparation of building blocks for synthesis of fluoroallylic compounds1
• Synthesis of alcohols via hydrolysis of alkyl silyl ethers at neutral pH in buffered mixed organic-aqueous solutions2
• Nucleophilic fluorination of alkynyliodonium salts to form fluorovinylic compounds3
• Nucleophilic aromatic substitution (SNAr) reactions4
包装
10, 50 g in poly bottle

REFERENCES