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(1S)-(+)-Menthyl chloroformate_Molecular_structure_CAS_7635-54-3)
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(1S)-(+)-Menthyl chloroformate

Catalog No. 378712 Name Sigma Aldrich
CAS Number 7635-54-3 Website http://www.sigmaaldrich.com
M. F. C11H19ClO2 Telephone 1-800-521-8956
M. W. 218.72036 Fax
Purity Email
Storage Chembase ID: 145997

SYNONYMS

Title
(1S)-(+)-氯甲酸薄荷酯
IUPAC name
(1S,2R,5S)-5-methyl-2-(propan-2-yl)cyclohexyl chloroformate
IUPAC Traditional name
(1S,2R,5S)-2-isopropyl-5-methylcyclohexyl chloroformate

DATABASE IDS

CAS Number 7635-54-3
MDL Number MFCD00134483
Beilstein Number 2414685
PubChem SID 24863571

PROPERTIES

Empirical Formula (Hill Notation) C11H19ClO2
Optical Purity ee: 97% (GLC)
Boiling Point 108-109 °C/11 mmHg(lit.)
Density 1.031 g/mL at 25 °C(lit.)
Flash Point 70 °C
Flash Point 158 °F
Optical Rotation [α]20/D +83°, c = 1 in chloroform
Refractive Index n20/D 1.458(lit.)
GHS Pictograms GHS05
GHS Pictograms GHS06
GHS Signal Word Danger
GHS Hazard statements H314-H331
European Hazard Symbols Toxic Toxic (T)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P280-P305 + P351 + P338-P310
RID/ADR UN 3277 6.1/PG 2
Risk Statements 23-34
Safety Statements 26-36/37/39-45
Storage Temperature 2-8°C
Hazard Class 6.1
UN Number 3277
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Packaging
5, 25 mL in glass bottle
Application
Chiral auxiliary in the asymmetric synthesis of quaternary carbon centers.1
Description (简体中文)
包装
5, 25 mL in glass bottle
Application
不对称合成季碳中心的手性助剂。1

REFERENCES