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Bis(trifluoromethane)sulfonimide lithium salt

Catalog No. 449504 Name Sigma Aldrich
CAS Number 90076-65-6 Website http://www.sigmaaldrich.com
M. F. C2F6LiNO4S2 Telephone 1-800-521-8956
M. W. 287.0871192 Fax
Purity Email
Storage Chembase ID: 12001

SYNONYMS

Title
双(三氟甲烷)磺酰亚胺 锂盐
IUPAC name
1,1,1-trifluoro-N-lithio-N-trifluoromethanesulfonylmethanesulfonamide
IUPAC Traditional name
1,1,1-trifluoro-N-lithio-N-trifluoromethanesulfonylmethanesulfonamide
Synonyms
双(三氟甲基磺酰)胺 锂盐
Bis(trifluoromethylsulfonyl)amine lithium salt
Lithium bistrifluoromethanesulfonimidate
双三氟甲烷磺酰亚胺锂

DATABASE IDS

EC Number 415-300-0
MDL Number MFCD00210017
PubChem SID 24868486
CAS Number 90076-65-6
Beilstein Number 6625414

PROPERTIES

Linear Formula CF3SO2NLiSO2CF3
Melting Point 234-238 °C(lit.)
GHS Pictograms GHS05
GHS Pictograms GHS06
GHS Pictograms GHS08
GHS Signal Word Danger
GHS Hazard statements H301 + H311-H314-H373-H412
European Hazard Symbols Toxic Toxic (T)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P273-P280-P301 + P310-P305 + P351 + P338-P310
RID/ADR UN 2923 8/PG 2
Risk Statements 24/25-34-48/22-52/53
Safety Statements 22-26-36/37/39-45-61
Hazard Class 8
UN Number 2923
Packing Group 2
German water hazard class 2

DETAILS

Description (English)
Application
Used in the preparation of a chiral imidazolium salt via anion metathesis of the corresponding triflate.1
Used in the preparation of electrolytes for lithium batteries and novel rare-earth Lewis acid catalysts.
Other Notes
For a review on fluorine containing nitrogen acids, see Coordination Chemistry Reviews.2
Packaging
10, 50 g in glass bottle
Description (简体中文)
Application
用于制备锂电池的电解质以及新型稀土路易斯酸催化剂。
用于通过对应的三氟甲基磺酸盐的阴离子置换反应制备手性咪唑鎓盐。1
Other Notes
关于含氟氮酸的综述,请参见 Coordination Chemistry Reviews。2
包装
10, 50 g in glass bottle

REFERENCES