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N-(Triphenylphosphoranylidene)-1H-benzotriazole-1-methanamine_Molecular_structure_CAS_124316-00-3)
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N-(Triphenylphosphoranylidene)-1H-benzotriazole-1-methanamine

Catalog No. 446939 Name Sigma Aldrich
CAS Number 124316-00-3 Website http://www.sigmaaldrich.com
M. F. C25H21N4P Telephone 1-800-521-8956
M. W. 408.434801 Fax
Purity 90% Email
Storage Chembase ID: 145950

SYNONYMS

Title
三甲基氯化亚砜
IUPAC name
(1H-1,2,3-benzotriazol-1-ylmethyl)(triphenyl-λ5-phosphanylidene)amine
IUPAC Traditional name
(1,2,3-benzotriazol-1-ylmethyl)(triphenyl-λ5-phosphanylidene)amine
Synonyms
Betmip
1-[[(Triphenylphosphoranylidene)amino]methyl]benzotriazole

DATABASE IDS

CAS Number 124316-00-3
MDL Number MFCD00274644
PubChem SID 24868307

PROPERTIES

Empirical Formula (Hill Notation) C25H21N4P
Impurities 10% N-(triphenylphosphoranylidene)-2H-benzotriazole-2-methanamine
Purity 90%
Melting Point 116-122 °C(lit.)
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Packaging
1 g in glass bottle
250 mg in glass bottle
Application
Reactant for:
• Grignard reaction1
• Preparation of N,N-Bis(but-3-enyl)amines via aza-Wittig reaction with aldehydes, followed by a double Grignard reaction with allylmagnesium bromide2
• Organic synthesis of N-alkyliminophosphoranes and a-functionalized N-alkyliminophosphoranes3
Description (简体中文)
包装
1 g in glass bottle
250 mg in glass bottle
Application
Reactant for:
• Grignard reaction1
• Preparation of N,N-Bis(but-3-enyl)amines via aza-Wittig reaction with aldehydes, followed by a double Grignard reaction with allylmagnesium bromide2
• Organic synthesis of N-alkyliminophosphoranes and a-functionalized N-alkyliminophosphoranes3

REFERENCES