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Copper(I) trifluoromethanesulfonate benzene complex_Molecular_structure_CAS_42152-46-5)
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Copper(I) trifluoromethanesulfonate benzene complex

Catalog No. 407240 Name Sigma Aldrich
CAS Number 42152-46-5 Website http://www.sigmaaldrich.com
M. F. C8H6Cu2F6O6S2 Telephone 1-800-521-8956
M. W. 503.3420592 Fax
Purity 90% Email
Storage Chembase ID: 145940

SYNONYMS

Title
三氟甲烷磺酸铜与苯的络合物
IUPAC name
bis(λ1-copper(1+) ion) benzene ditrifluoromethanesulfonate
IUPAC Traditional name
bis(λ1-copper(1+) ion) benzene ditriflate
Synonyms
三氟甲磺酸铜苯络合物
Cuprous trifluoromethanesulfonate benzene complex
三氟甲烷磺酸铜盐苯络合物
Trifluoromethanesulfonic acid copper(I) salt benzene complex
Copper(I) triflate benzene complex
三氟甲烷磺酸铜苯络合物

DATABASE IDS

CAS Number 42152-46-5
EC Number 255-686-6
MDL Number MFCD00043300
PubChem SID 24865435

PROPERTIES

Grade technical grade
Linear Formula (CF3SO3Cu)2 · C6H6
Purity 90%
Flash Point 7 °C
Flash Point 44.6 °F
Melting Point 160 °C (dec.)(lit.)
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H315-H319-H335
European Hazard Symbols Flammable Flammable (F)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P261-P305 + P351 + P338
RID/ADR UN 3175 4.1/PG 2
Risk Statements 11-36/37/38
Safety Statements 16-26-36
Hazard Class 4.1
UN Number 3175
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Application
In combination with amino acid-based chiral phosphine ligands, catalyzes asymmetric conjugate additions of alkylzincs to acyclic α,β-unsaturated ketones, affording β-alkylcarbonyls in high yield and with excellent enantioselectivity.1 Catalyzes allylic oxidation of cyclic alkenes enantioselectively.2
Packaging
1, 5 g in glass bottle
Description (简体中文)
Application
与氨基酸型手性膦配体结合,催化烷基锌不对称共轭加成为无环 α,β-不饱和酮,生成高产量并且具有优异对映选择性的 β-烷基羰基化物。1对映选择性催化环烯烃的烯丙基氧化反应。2
包装
1, 5 g in glass bottle

REFERENCES