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(S)-(-)-2-Acetoxypropionyl chloride_Molecular_structure_CAS_36394-75-9)
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(S)-(-)-2-Acetoxypropionyl chloride

Catalog No. 447056 Name Sigma Aldrich
CAS Number 36394-75-9 Website http://www.sigmaaldrich.com
M. F. C5H7ClO3 Telephone 1-800-521-8956
M. W. 150.56028 Fax
Purity 97% Email
Storage Chembase ID: 145841

SYNONYMS

Title
(S)-(-)-2-乙酰氧基丙酰氯
IUPAC name
(2S)-1-chloro-1-oxopropan-2-yl acetate
IUPAC Traditional name
(2S)-1-chloro-1-oxopropan-2-yl acetate
Synonyms
2-过氧乙酰丙酰氯
AP-Cl
O-Acetyl-L-lactyl chloride

DATABASE IDS

Beilstein Number 1722943
PubChem SID 24868317
CAS Number 36394-75-9
MDL Number MFCD00145252

PROPERTIES

Linear Formula CH3CH(O2CCH3)COCl
Purity 97%
Boiling Point 50 °C/5 mmHg(lit.)
Density 1.189 g/mL at 25 °C(lit.)
Flash Point 113 °C
Flash Point 235.4 °F
Optical Rotation [α]20/D -31°, c = 4 in chloroform
Refractive Index n20/D 1.423(lit.)
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3265 8/PG 2
Risk Statements 34
Safety Statements 26-36/37/39-45
Hazard Class 8
UN Number 3265
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Packaging
1, 5 g in glass bottle
Application
Frequently used chiral building block.1,2 Also used to resolve a bicyclic α-hydroxylactone3 and to prepare chiral phosphonates used in an enantiomeric excess assay of unprotected amino acids.4 Useful chiral derivatizing agent.5
Description (简体中文)
包装
1, 5 g in glass bottle
Application
常用手性结构单元。1,2也用于分解二环α-羟基内酯3以及制备手性膦酸酯,以用于无保护氨基酸的对映体过量检测。4有效的手性衍生剂。5

REFERENCES