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Methyl dichlorophosphite_Molecular_structure_CAS_3279-26-3)
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Methyl dichlorophosphite

Catalog No. 235229 Name Sigma Aldrich
CAS Number 3279-26-3 Website http://www.sigmaaldrich.com
M. F. CH3Cl2OP Telephone 1-800-521-8956
M. W. 132.913681 Fax
Purity Email
Storage Chembase ID: 145781

SYNONYMS

Title
二氯亚磷酸甲酯
IUPAC name
methyl dichlorophosphinite
IUPAC Traditional name
methyl dichlorophosphinite
Synonyms
Methyl phosphorodichloridite
甲氧基二氯化膦

DATABASE IDS

PubChem SID 24854089
CAS Number 3279-26-3
Beilstein Number 1697452
EC Number 221-915-3
MDL Number MFCD00000524

PROPERTIES

Grade technical grade
Linear Formula CH3OPCl2
Boiling Point 93-95 °C(lit.)
Density 1.376 g/mL at 20 °C(lit.)
Flash Point 25 °C
Flash Point 77 °F
Melting Point -91 °C(lit.)
Refractive Index n20/D 1.474(lit.)
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H226-H314-H335
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P280-P305 + P351 + P338-P310
RID/ADR UN 2920 8/PG 2
Risk Statements 10-14-34-37
Safety Statements 26-36/37/39-45
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 8
UN Number 2920
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Packaging
10, 50 g in ampule
Application
Employed in the synthesis of phosphorodichloridothioates1 and oxazaphosphorinanes2 from sulfenyl chlorides and a chiral amino alcohol, respectively.
Description (简体中文)
包装
10, 50 g in ampule
Application
用于分别从亚磺酰氯和手性氨基醇合成硫代二氯磷酸酯1以及氮氧杂膦烷2。

REFERENCES