Pentamethylcyclopentadienylrhodium(III) chloride dimer

• Catalog No.: 338370
• CAS Number: 12354-85-7
• M. F.: C20H30Cl4Rh2
• M. W.: 618.0752
• Purity: 97%

SYNONYMS

• Title: 二氯(五甲基环戊二烯基)合铑(III)二聚体
• IUPAC name: bis(dichlororhodiumylium); bis(pentamethylcyclopenta-2,4-dien-1-ide)
• IUPAC Traditional name: bis(dichlororhodiumylium); bis(pentamethylcyclopenta-2,4-dien-1-ide)
• Synonyms: 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex; Bis(pentamethylcyclopentadienylrhodium dichloride); Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer; Bis(dichloro(pentamethylcyclopentadienyl)rhodium); Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium

DATABASE IDS

• CAS Number: 12354-85-7
• PubChem SID: 24860540
• MDL Number: MFCD00061552

PROPERTIES

• Linear Formula: [Rh(C5Me5)Cl2]2
• Purity: 97%
• GHS Signal Word: Warning
• GHS Hazard statements: H302-H312-H315-H319-H332-H335
• European Hazard Symbols: Harmful (Xn)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P280-P305 + P351 + P338
• Risk Statements: 20/21/22-36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1 g in glass bottle
250 mg in glass bottle
Application
Umicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for:
• Oxidative olefination reactions1
• C-C bond cleavage of secondary alcohols2
• Ortho C-H olefination of phenol derivatives3
• Oxidative annulation of pyridines4
• Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond5
• Amidation reactions6
• Reductive alkylation reactions7

Description (简体中文)

包装
1 g in glass bottle
250 mg in glass bottle
Application
Umicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for:
• Oxidative olefination reactions1
• C-C bond cleavage of secondary alcohols2
• Ortho C-H olefination of phenol derivatives3
• Oxidative annulation of pyridines4
• Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond5
• Amidation reactions6
• Reductive alkylation reactions7