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1-Bromocarbonyl-1-methylethyl acetate_Molecular_structure_CAS_40635-67-4)
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1-Bromocarbonyl-1-methylethyl acetate

Catalog No. 364878 Name Sigma Aldrich
CAS Number 40635-67-4 Website http://www.sigmaaldrich.com
M. F. C6H9BrO3 Telephone 1-800-521-8956
M. W. 209.03786 Fax
Purity 96% Email
Storage Chembase ID: 145622

SYNONYMS

Title
乙酸 1-溴羰基-1-甲基乙酯
IUPAC name
1-bromo-2-methyl-1-oxopropan-2-yl acetate
IUPAC Traditional name
1-bromo-2-methyl-1-oxopropan-2-yl acetate
Synonyms
α-Acetoxyisobutyryl bromide
α-乙酰氧基异丁酰溴
2-Acetoxy-2-methylpropionyl bromide
2-乙酰氧基异丁酰溴

DATABASE IDS

MDL Number MFCD00040923
Beilstein Number 2432585
CAS Number 40635-67-4
PubChem SID 24862463

PROPERTIES

Linear Formula CH3COOC(CH3)2COBr
Purity 96%
Boiling Point 75-77 °C/12 mmHg(lit.)
Density 1.431 g/mL at 25 °C(lit.)
Flash Point 113 °C
Flash Point 235.4 °F
Refractive Index n20/D 1.457(lit.)
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H314-H335
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P280-P305 + P351 + P338-P310
RID/ADR UN 3265 8/PG 2
Risk Statements 14-34-37
Safety Statements 26-36/37/39-45
Storage Temperature 2-8°C
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 8
UN Number 3265
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Application
Reagent for deoxygenation of vicinal diols, as well as in the preparation of 2′,3′-dideoxycytidine and other dideoxy and deoxynucleosides from the corresponding ribo series.1
Packaging
25, 100 g in glass bottle
Description (简体中文)
Application
用于邻二醇脱氧反应的试剂,也可用于由对应的系列核糖核苷制备 2′,3′-二脱氧胞嘧啶核苷和其他二脱氧核苷和脱氧核苷。1
包装
25, 100 g in glass bottle

REFERENCES