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N-(5-Chloro-2-pyridyl)bis(trifluoromethanesulfonimide)_Molecular_structure_CAS_145100-51-2)
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N-(5-Chloro-2-pyridyl)bis(trifluoromethanesulfonimide)

Catalog No. 403644 Name Sigma Aldrich
CAS Number 145100-51-2 Website http://www.sigmaaldrich.com
M. F. C7H3ClF6N2O4S2 Telephone 1-800-521-8956
M. W. 392.6831392 Fax
Purity 96% Email
Storage Chembase ID: 18909

SYNONYMS

Title
N-(5-氯-2-吡啶基)双(三氟甲烷磺酰亚胺)
IUPAC name
N-(5-chloropyridin-2-yl)-1,1,1-trifluoro-N-trifluoromethanesulfonylmethanesulfonamide
IUPAC Traditional name
N-(5-chloropyridin-2-yl)-1,1,1-trifluoro-N-trifluoromethanesulfonylmethanesulfonamide
Synonyms
2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine
N,N-双(三氟甲基磺酰)-5-氯-2-吡啶胺
2-[N,N-双(三氟甲基磺酰)氨基]-5-氯吡啶
Comins’ Reagent
N,N-Bis(trifluoromethylsulfonyl)-5-chloro-2-pyridylamine
Comins 试剂

DATABASE IDS

PubChem SID 24865208
MDL Number MFCD00191833
Beilstein Number 5833971
CAS Number 145100-51-2

PROPERTIES

Empirical Formula (Hill Notation) C7H3ClF6N2O4S2
Purity 96%
Melting Point 45-47 °C(lit.)
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
Storage Temperature 2-8°C
German water hazard class 3

DETAILS

Description (English)
Packaging
1, 5 g in glass bottle
Application
Provides good yields of vinyl triflates from the corresponding ketone enolates or dienolates.1,2,3
Reactant for: Suzuki-Miyaura cross coupling Synthesis of nicotinic acetylcholine receptor-selective ligands Enantioselective desymmetrizing palladium catalyzed carbonylation reactions Synthesis of high affinity niacin receptor GPR109A agonists Preparation of heteroaromatics
Description (简体中文)
包装
1, 5 g in glass bottle
Application
Reactant for: Suzuki-Miyaura cross coupling Synthesis of nicotinic acetylcholine receptor-selective ligands Enantioselective desymmetrizing palladium catalyzed carbonylation reactions Synthesis of high affinity niacin receptor GPR109A agonists Preparation of heteroaromatics
用于由对应的酮烯醇化物或二烯醇化物生成高产率的三氟甲磺酸乙烯酯。1,2,3

REFERENCES