(1S)-(+)-Ketopinic acid

• Catalog No.: 420964
• CAS Number: 40724-67-2
• M. F.: C10H14O3
• M. W.: 182.21636
• Purity: 99%

SYNONYMS

• Title: (1S)-(+)-酮基蒎酸
• IUPAC name: (1S,4R)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
• IUPAC Traditional name: (1S,4R)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
• Synonyms: (1S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid; (1S)-7,7-二甲基-2-氧代二环[2.2.1]庚烷-1-甲酸

DATABASE IDS

• PubChem SID: 24866367
• CAS Number: 40724-67-2
• MDL Number: MFCD00168053
• Beilstein Number: 4180005

PROPERTIES

• Empirical Formula (Hill Notation): C10H14O3
• Purity: 99%
• Melting Point: 237-239 °C(lit.)
• Optical Rotation: [α]23/D +58°, c = 1 in chloroform
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1 g in glass bottle
Application
Used to prepare a new chiral oxazolidone auxiliary1 and a ketopinic derivatized polymer used for the deracemization of amines.2 Starting material for the synthesis of homochiral 2,10-camphanediols.3 Employed in the formation of a chiral Schiff base precursor to diethyl (S)-α-amino-α-alkyl phosphonates.4

Description (简体中文)

包装
1 g in glass bottle
Application
用于制备新型手性噁唑烷酮辅助剂1和酮基蒎酸衍生聚合物，该聚合物可用于胺的去外消旋化。2合成纯手性 2,10-莰烷二醇的原料。3用于生成手性席夫碱前体，以制备二乙基 (S)-α-氨基-α-烷基膦酸酯。4