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(1S)-(+)-Ketopinic acid_Molecular_structure_CAS_40724-67-2)
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(1S)-(+)-Ketopinic acid

Catalog No. 420964 Name Sigma Aldrich
CAS Number 40724-67-2 Website http://www.sigmaaldrich.com
M. F. C10H14O3 Telephone 1-800-521-8956
M. W. 182.21636 Fax
Purity 99% Email
Storage Chembase ID: 145405

SYNONYMS

Title
(1S)-(+)-酮基蒎酸
IUPAC name
(1S,4R)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
IUPAC Traditional name
(1S,4R)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
Synonyms
(1S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid
(1S)-7,7-二甲基-2-氧代二环[2.2.1]庚烷-1-甲酸

DATABASE IDS

PubChem SID 24866367
CAS Number 40724-67-2
MDL Number MFCD00168053
Beilstein Number 4180005

PROPERTIES

Empirical Formula (Hill Notation) C10H14O3
Purity 99%
Melting Point 237-239 °C(lit.)
Optical Rotation [α]23/D +58°, c = 1 in chloroform
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Packaging
1 g in glass bottle
Application
Used to prepare a new chiral oxazolidone auxiliary1 and a ketopinic derivatized polymer used for the deracemization of amines.2 Starting material for the synthesis of homochiral 2,10-camphanediols.3 Employed in the formation of a chiral Schiff base precursor to diethyl (S)-α-amino-α-alkyl phosphonates.4
Description (简体中文)
包装
1 g in glass bottle
Application
用于制备新型手性噁唑烷酮辅助剂1和酮基蒎酸衍生聚合物,该聚合物可用于胺的去外消旋化。2合成纯手性 2,10-莰烷二醇的原料。3用于生成手性席夫碱前体,以制备二乙基 (S)-α-氨基-α-烷基膦酸酯。4

REFERENCES