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Bis(trimethylsilyl)acetylene

Catalog No. 187437 Name Sigma Aldrich
CAS Number 14630-40-1 Website http://www.sigmaaldrich.com
M. F. C8H18Si2 Telephone 1-800-521-8956
M. W. 170.39952 Fax
Purity 99% Email
Storage Chembase ID: 126168

SYNONYMS

Title
双(三甲基甲硅烷基)乙炔
IUPAC name
trimethyl[2-(trimethylsilyl)ethynyl]silane
IUPAC Traditional name
bis(trimethylsilyl)acetylene
Synonyms
BTMSA

DATABASE IDS

Beilstein Number 906870
PubChem SID 24851275
MDL Number MFCD00008276
CAS Number 14630-40-1
EC Number 238-671-9

PROPERTIES

Linear Formula (CH3)3SiC≡CSi(CH3)3
Purity 99%
Boiling Point 136-137 °C(lit.)
Density 0.752 g/mL at 25 °C(lit.)
Flash Point 2 °C
Flash Point 35.6 °F
Melting Point 21-24 °C(lit.)
Refractive Index n20/D 1.427(lit.)
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H315-H319-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P261-P305 + P351 + P338
RID/ADR UN 1993 3/PG 2
Risk Statements 11-36/37/38
Safety Statements 16-26-36
Storage Temperature 2-8°C
Hazard Class 3
UN Number 1993
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Packaging
10, 50 g in glass bottle
Application
In the presence of CpCo(CO)2 (cat. no. 245259), undergoes cycloaddition with 1,5-hexadiynes to form benzocyclobutenes.1
Description (简体中文)
包装
10, 50 g in glass bottle
Application
在 CpCo(CO)2(产品目录号245259)存在的条件下,可与 1,5-己二炔发生环加成反应生成苯并环丁烯。1

REFERENCES