Vanadium(V) oxytriisopropoxide

• Catalog No.: 404926
• CAS Number: 5588-84-1
• M. F.: C9H21O4V
• M. W.: 244.20214

SYNONYMS

• Title: 三异丙氧基氧化钒(V)
• IUPAC name: oxotris(propan-2-yloxy)vanadium
• IUPAC Traditional name: triisopropoxy(oxo)vanadium
• Synonyms: VTIP; 三异丙醇氧钒(V); Vanadium(V) trisisopropoxide oxide; Triisopropoxyvanadium(V) oxide; 三异丙氧基氧化钒

DATABASE IDS

• CAS Number: 5588-84-1
• PubChem SID: 24865281
• MDL Number: MFCD00015017
• EC Number: 226-997-4

PROPERTIES

• Linear Formula: OV(OCH(CH3)2)3
• Apperance: liquid
• Boiling Point: 80-82 °C/2 mmHg(lit.)
• Density: 1.035 g/mL at 25 °C(lit.)
• Flash Point: 45 °C
• Flash Point: 113 °F
• Refractive Index: n20/D 1.479(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H226-H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P261-P305 + P351 + P338
• RID/ADR: UN 1993 3/PG 3
• Risk Statements: 10-36/37/38
• Safety Statements: 16-26-27
• Hazard Class: 3
• UN Number: 1993
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1, 10 g in glass bottle
Application
Building block for a series of neutral oxovanadium complexes containing both ethoxide and acetylacetonate ligands the complexes have potential biological relevance as well as uses in catalysis.1
Protocols & Applications
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Asymmetric Ketone Hydrogenation
Asymmetric Transfer Hydrogenation

Description (简体中文)

包装
1, 10 g in glass bottle
Application
一系列中性氧钒配合物的结构单元，包括乙醇盐和乙酰丙酮化物配体。这些配合物具有潜在的生物相关性并用于催化作用。1
Protocols & Applications
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Asymmetric Ketone Hydrogenation
Asymmetric Transfer Hydrogenation