Tris(2,6-dimethoxyphenyl)phosphine

• Catalog No.: 393436
• CAS Number: 85417-41-0
• M. F.: C24H27O6P
• M. W.: 442.441341
• Purity: 98%

SYNONYMS

• Title: 三(2,6-二甲氧基苯)膦
• IUPAC name: tris(2,6-dimethoxyphenyl)phosphane
• IUPAC Traditional name: tris(2,6-dimethoxyphenyl)phosphane
• Synonyms: DMPP

DATABASE IDS

• MDL Number: MFCD00192558
• PubChem SID: 24864518
• CAS Number: 85417-41-0

PROPERTIES

• Linear Formula: [(CH3O)2C6H3]3P
• Purity: 98%
• Melting Point: 145-147 °C(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-37/39
• German water hazard class: 3

DETAILS

Description (English)

Packaging
5 g in glass bottle
Application
Catalyst for:
• Preparation of chiral building blocks via hydroalkynylation reactions or ynolates1
• Three-component aza-Morita-Baylis-Hillman reactions (aza-MBH)2
• Atom-economic synthesis of nitrogen heterocycles and ynenoates from alkynes3
• Oxycylizations of allendiols4
• Enantioselective aldol reactions5
• Pd-mediated cross-coupling, Pd- and Cu-mediated benzannulation reactions and copper-mediated dimerization reactions6

Description (简体中文)

包装
5 g in glass bottle
Application
Catalyst for:
• Preparation of chiral building blocks via hydroalkynylation reactions or ynolates1
• Three-component aza-Morita-Baylis-Hillman reactions (aza-MBH)2
• Atom-economic synthesis of nitrogen heterocycles and ynenoates from alkynes3
• Oxycylizations of allendiols4
• Enantioselective aldol reactions5
• Pd-mediated cross-coupling, Pd- and Cu-mediated benzannulation reactions and copper-mediated dimerization reactions6