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Bromopentacarbonylrhenium(I)_Molecular_structure_CAS_14220-21-4)
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Bromopentacarbonylrhenium(I)

Catalog No. 327638 Name Sigma Aldrich
CAS Number 14220-21-4 Website http://www.sigmaaldrich.com
M. F. C5BrO5Re Telephone 1-800-521-8956
M. W. 406.1615 Fax
Purity 98% Email
Storage Chembase ID: 145105

SYNONYMS

Title
溴代五羰基铼(I)
IUPAC name
bromorhenium; pentakis(methanidylidyneoxidanium)
IUPAC Traditional name
bromorhenium; pentakis(carbon monoxide)
Synonyms
Pentacarbonylrhenium bromide
五羰基溴铼(I)
Pentacarbonylbromorhenium
Rhenium(I) pentacarbonyl bromide

DATABASE IDS

MDL Number MFCD00013295
CAS Number 14220-21-4
EC Number 238-084-8
PubChem SID 24859676

PROPERTIES

Linear Formula Re(CO)5Br
Purity 98%
GHS Pictograms GHS06
GHS Signal Word Danger
GHS Hazard statements H301-H311-H315-H319-H331-H335
European Hazard Symbols Toxic Toxic (T)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
GHS Precautionary statements P261-P280-P301 + P310-P305 + P351 + P338-P311
RID/ADR UN 3288 6.1/PG 3
Risk Statements 23/24/25-36/37/38
Safety Statements 26-28-36/37/39-45
Hazard Class 6.1
UN Number 3288
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Application
Starting material for rhenium-polypyridine complexes that have potential applications in catalysis and solar energy conversion.3
Used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands.
Used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands1 and also to prepare [3]-ferrocenophane complexes.2
Packaging
1 g in glass bottle
Description (简体中文)
Application
用于研究三羰基环铼和二亚胺配体形成的 π-缺电子络合物。
铼-多吡啶络合物的原料,这种络合物在催化和太阳能转化中具有应用前景。3
用于研究三羰基环铼和二亚胺配体形成的 π-缺电子络合物1,也可用于制备 [3]-二茂铁吩络合物。2
包装
1 g in glass bottle

REFERENCES