(5S)-(-)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride

• Catalog No.: 569763
• CAS Number: 278173-23-2
• M. F.: C13H19ClN2O
• M. W.: 254.75576
• Purity: 97%

SYNONYMS

• Title: (5S)-(-)-2,2,3-三甲基-5-苄基-4-咪唑啉酮 单盐酸盐
• IUPAC name: (5S)-5-benzyl-2,2,3-trimethylimidazolidin-4-one hydrochloride
• IUPAC Traditional name: (5S)-5-benzyl-2,2,3-trimethylimidazolidin-4-one hydrochloride

DATABASE IDS

• MDL Number: MFCD03426983
• CAS Number: 278173-23-2
• PubChem SID: 24880521

PROPERTIES

• Empirical Formula (Hill Notation): C13H18N2O · HCl
• Purity: 97%
• Melting Point: 157-161 °C(lit.)
• Optical Rotation: [α]20/D -67°, c = 1 in H2O
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Metal-free OrganoCatalyst technology for asymmetric catalysis. Catalyzes asymmetric Diels-Alder reactions, 1,3-dipolar additions and pyrrole alkylations in high enantiomeric excess.1,2,3
Used in first highly enantioselective organocatalytic Diels-Alder reaction and 1,3-dipolar addition.
Packaging
2 g in glass bottle
500 mg in glass bottle
Legal Information
U.S. Pat. 6,369,243 and related patents apply. For research purposes only.
Protocols & Applications
Metal-free Asymmetric Catalysis using Macmillan Imidazolidinone Organocatalysts

Description (简体中文)

Application
用于不对称催化反应的无金属 OrganoCatalyst 技术。以高对映体过剩率催化不对称 Diels-Alder 反应、1,3-偶极加成反应和吡咯烷基化反应。1,2,3
用于首例高对映选择性有机催化 Diels-Alder 反应和 1,3-偶极加成。
包装
2 g in glass bottle
500 mg in glass bottle
Legal Information
适用美国专利6,369,243 和相关专利。仅供研究使用。
Protocols & Applications
Metal-free Asymmetric Catalysis using Macmillan Imidazolidinone Organocatalysts