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Chromium(II) chloride

Catalog No. 450782 Name Sigma Aldrich
CAS Number 10049-05-5 Website http://www.sigmaaldrich.com
M. F. Cl2Cr Telephone 1-800-521-8956
M. W. 122.9021 Fax
Purity 99.99% trace metals basis Email
Storage Chembase ID: 109484

SYNONYMS

Title
氯化铬(II)
IUPAC name
dichlorochromium
IUPAC Traditional name
chromium(II) chloride
Synonyms
Chromium dichloride
Chromous chloride

DATABASE IDS

CAS Number 10049-05-5
PubChem SID 24868545
EC Number 233-163-3
MDL Number MFCD00010947

PROPERTIES

Grade anhydrous
Linear Formula CrCl2
Purity 99.99% trace metals basis
Apperance powder
Density 2.9 g/mL at 25 °C(lit.)
Melting Point 824 °C(lit.)
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H302-H315-H319-H335
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 22-36/37/38
RTECS GB5250000
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Application
Mediates the condensation of the aldehydes with trisubstituted chloroalkenes.1 Used in the synthesis of a highly active precatalyst for ethylene oligimerization.2
Used to make bis(indenyl)chromium dimer and related products.
Used with iodoform and tetraethyl ethylenediamine to convert terminal olefins into trans-iodocyclopropanes in excellent yields.
The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties.
Packaging
1, 5, 25 g in ampule
Description (简体中文)
Application
与碘仿和四乙基乙二胺一起使用,将末端烯烃以高产率转化成反式碘代环丙烷。
用于制备双(茚基)铬二聚体和相关产品。
调控醛与三取代氯烯烃的缩合。1用于合成乙烯低聚反应所需的高活性预催化剂。2
在氢作用下与其他金属卤化物气相共还原生成细分的金属互化物,它们可用作具有有效的热电性、磁性和抗氧化性的结构材料或化合物。
包装
1, 5, 25 g in ampule

REFERENCES