Tris(dibenzylideneacetone)dipalladium(0)

• Catalog No.: 328774
• CAS Number: 51364-51-3
• M. F.: C51H42O3Pd2
• M. W.: 915.71738
• Purity: 97%

SYNONYMS

• Title: 三(二亚苄基丙酮)二钯(0)
• IUPAC name: tris(1,5-diphenylpenta-1,4-dien-3-one) dipalladium
• IUPAC Traditional name: tris(dibenzylideneacetone) dipalladium
• Synonyms: Pd2(dba)3; Pd2dba3

DATABASE IDS

• PubChem SID: 24859746
• CAS Number: 51364-51-3
• MDL Number: MFCD00013310

PROPERTIES

• Linear Formula: (C6H5CH=CHCOCH=CHC6H5)3Pd2
• Purity: 97%
• Melting Point: 152-155 °C(lit.)
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 2

DETAILS

Description (English)

Packaging
1, 5, 25, 50, 100 g in glass bottle
500 mg in glass bottle
Application

• Catalyst for Suzuki coupling of aryl chlorides (eq. 1)
• Catalyst for Heck coupling of aryl chlorides (eq. 2)
• Catalyst for arylation of ketones (eq. 3)
• Catalyst for Buchwald-Hartwig amination of aryl halides (eq. 4)
• Catalyst for fluorination of allylic chlorides (eq. 5)
• Catalyst for β-arylation of carboxylic esters (eq. 6)
• Catalyst for carbonylation of 1,1-dichloro-1-alkenes (eq. 7)
• Catalyst for conversion of aryl and vinyl triflates to aryl and vinyl halides (eq. 8)
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsReactant involved in:
• Synthesis of nanosized palladium phosphides upon interaction with white phosphorous1
• Preparation of palladium triphenylphosphine carbonyl cluster complexes2
• Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions3
• Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynes4Catalyst for:
• Suzuki cross-coupling reactions5
• PCN- and PCS-pincer palladium complex catalyzed tandem allylation6

Description (简体中文)

包装
1, 5, 25, 50, 100 g in glass bottle
500 mg in glass bottle
Application

• Catalyst for Suzuki coupling of aryl chlorides (eq. 1)
• Catalyst for Heck coupling of aryl chlorides (eq. 2)
• Catalyst for arylation of ketones (eq. 3)
• Catalyst for Buchwald-Hartwig amination of aryl halides (eq. 4)
• Catalyst for fluorination of allylic chlorides (eq. 5)
• Catalyst for β-arylation of carboxylic esters (eq. 6)
• Catalyst for carbonylation of 1,1-dichloro-1-alkenes (eq. 7)
• Catalyst for conversion of aryl and vinyl triflates to aryl and vinyl halides (eq. 8)
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsReactant involved in:
• Synthesis of nanosized palladium phosphides upon interaction with white phosphorous1
• Preparation of palladium triphenylphosphine carbonyl cluster complexes2
• Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions3
• Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynes4Catalyst for:
• Suzuki cross-coupling reactions5
• PCN- and PCS-pincer palladium complex catalyzed tandem allylation6