Pentacarbonylchlororhenium(I)

• Catalog No.: 327611
• CAS Number: 14099-01-5
• M. F.: C5ClO5Re
• M. W.: 361.7105
• Purity: 98%

SYNONYMS

• Title: 五羰基氯铼(I)
• IUPAC name: chlororhenium; pentakis(methanidylidyneoxidanium)
• IUPAC Traditional name: pentakis(carbon monoxide); chlororhenium
• Synonyms: Rhenium(I) pentacarbonyl chloride; 氯代五羰基铼(I)

DATABASE IDS

• EC Number: 237-948-1
• PubChem SID: 24859674
• CAS Number: 14099-01-5
• MDL Number: MFCD00013296

PROPERTIES

• Linear Formula: Re(CO)5Cl
• Purity: 98%
• GHS Signal Word: Danger
• GHS Hazard statements: H301-H311-H315-H319-H331-H335
• European Hazard Symbols: Toxic (T)
• Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
• GHS Precautionary statements: P261-P280-P301 + P310-P305 + P351 + P338-P311
• RID/ADR: UN 3288 6.1/PG 3
• Risk Statements: 23/24/25-36/37/38
• Safety Statements: 26-28-36/37/39-45
• Hazard Class: 6.1
• UN Number: 3288
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
For a review of organometallic complexes of rhenium, see Science of Synthesis.4
Packaging
1, 5 g in glass bottle
Application
Used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands1 and also to prepare [3]-ferrocenophane complexes.2 Employed in preparation of a series of mixed-valence compounds of rhenium and iron these compounds find application in the study of charge-transfer processes.3

Description (简体中文)

Other Notes
关于铼的有机金属络合物的综述，请参阅 Science of Synthesis。4
包装
1, 5 g in glass bottle
Application
用于研究三羰基卤代铼与二亚胺配体间形成的缺 π-电子络合物1，也可用于制备 [3]-二茂铁环蕃络合物。2用于制备一系列的铼、铁混合价化合物，这些化合物可用于研究电荷转移过程。3