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Tris(acetonitrile)tricarbonyltungsten(0)_Molecular_structure_CAS_16800-47-8)
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Tris(acetonitrile)tricarbonyltungsten(0)

Catalog No. 540706 Name Sigma Aldrich
CAS Number 16800-47-8 Website http://www.sigmaaldrich.com
M. F. C9H9N3O3W Telephone 1-800-521-8956
M. W. 391.02606 Fax
Purity Email
Storage Chembase ID: 144841

SYNONYMS

Title
三(乙酰腈)三羰基钨(0)
IUPAC name
tris(acetonitrile) tris(methanidylidyneoxidanium) tungsten
IUPAC Traditional name
tris(acetonitrile) tris(carbon monoxide) tungsten
Synonyms
Tris(acetonitrile)tungsten(0)
三(乙腈)钨(0)

DATABASE IDS

PubChem SID 24878491
MDL Number MFCD00054393
CAS Number 16800-47-8
EC Number 240-833-9

PROPERTIES

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Pictograms GHS06
GHS Signal Word Danger
GHS Hazard statements H300-H310-H330
European Hazard Symbols Highly toxic Highly toxic (T+)
MSDS Link Download
GHS Precautionary statements P260-P264-P280-P284-P302 + P350-P310
RID/ADR UN 3466 6.1/PG 1
Risk Statements 26/27/28
RTECS YO7800000
Safety Statements 7/9-28-36/37-45
Hazard Class 6.1
UN Number 3466
Packing Group 1
German water hazard class 3
Linear Formula W(NCCH3)3(CO)3
Melting Point >300 °C(lit.)

DETAILS

Description (English)
Packaging
5 g in glass bottle
Application
Catalyst for allylic substitutions1Reactant for:
• Mixed disilyl-substituted cyclopentadiene derivatives2
• Synthesis of catalytically active ansa compounds with cycloalkyl moieties3
• Stepwise assembly of mixed metal dinuclear carbonyl complexes4
• Cycloaddition of M(CO)3-coordinated-cyanoazepine with alkynes5
Description (简体中文)
包装
5 g in glass bottle
Application
Catalyst for allylic substitutions1Reactant for:
• Mixed disilyl-substituted cyclopentadiene derivatives2
• Synthesis of catalytically active ansa compounds with cycloalkyl moieties3
• Stepwise assembly of mixed metal dinuclear carbonyl complexes4
• Cycloaddition of M(CO)3-coordinated-cyanoazepine with alkynes5

REFERENCES