(S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate

• Catalog No.: 248940
• CAS Number: 35193-64-7
• M. F.: C20H13O4P
• M. W.: 348.288581
• Purity: 97%

SYNONYMS

• Title: S-联萘酚磷酸酯
• IUPAC name: 13-hydroxy-12,14-dioxa-13λ^5-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-one
• IUPAC Traditional name: 13-hydroxy-12,14-dioxa-13λ^5-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-one
• Synonyms: (S)-(+)-1,1′-联萘-2,2′-二基磷酸氢酯; (S)-(+)-1,1′-Binaphthalene-2,2′-diyl hydrogen phosphate; (S)-4-羟基二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英-4-氧化物; (S)-4-Hydroxydinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

DATABASE IDS

• MDL Number: MFCD00010045
• Beilstein Number: 4787775
• PubChem SID: 24854963
• CAS Number: 35193-64-7

PROPERTIES

• Empirical Formula (Hill Notation): C20H13O4P
• Purity: 97%
• Optical Rotation: [α]22/D +595°, c = 1.35 in methanol
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Used as a chiral Bronsted acid catalyst in the enantoselective Mannich reaction.1
Packaging
1, 5 g in glass bottle
Protocols & Applications
Reductive Amination using BINOL-Derived Chiral Phosphoric Acids

Description (简体中文)

Application
用作不对称 Mannich 反应中手性布朗斯特酸催化剂。1
包装
1, 5 g in glass bottle
Protocols & Applications
Reductive Amination using BINOL-Derived Chiral Phosphoric Acids