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[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)_Molecular_structure_CAS_14647-23-5)
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[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)

Catalog No. 328219 Name Sigma Aldrich
CAS Number 14647-23-5 Website http://www.sigmaaldrich.com
M. F. C26H24Cl2NiP2 Telephone 1-800-521-8956
M. W. 528.015682 Fax
Purity Email
Storage Chembase ID: 144811

SYNONYMS

Title
[1,2-双(二苯基膦)乙烷]二氯化镍(II)
IUPAC name
[2-(diphenylphosphanyl)ethyl]diphenylphosphane; dichloronickel
IUPAC Traditional name
diphos; nickel chloride
Synonyms
[1,2-Bis(diphenylphosphino)ethane]nickel(II) chloride
Nickel 1,2-Bis(diphenylphosphino)ethane dichloride
1,2-Ethylenebis(diphenylphosphine)nickel dichloride
dppeNiCl2

DATABASE IDS

PubChem SID 24859721
MDL Number MFCD00013313
CAS Number 14647-23-5

PROPERTIES

Linear Formula [(C6H5)2PCH2CH2P(C6H5)2]NiCl2
Melting Point 263-265 °C(lit.)
GHS Pictograms GHS07
GHS Pictograms GHS08
GHS Signal Word Danger
GHS Hazard statements H302-H312-H315-H319-H332-H334-H335-H350
European Hazard Symbols Toxic Toxic (T)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
GHS Precautionary statements P201-P261-P280-P305 + P351 + P338-P308 + P313
Risk Statements 45-20/21/22-36/37/38-42/43
Safety Statements 53-22-26-36-45
German water hazard class 3

DETAILS

Description (English)
Packaging
1, 5, 25 g in glass bottle
Application
Reactant involved in:
• Kumada catalyst-transfer polycondensation1
• Oxidation of carboranyl phosphine ligands2
• Synthesis of nickel-iron dithiolato hydrides3
• Ullmann reactions - homocoupling reactions4Co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers5Catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes6
Description (简体中文)
包装
1, 5, 25 g in glass bottle
Application
Reactant involved in:
• Kumada catalyst-transfer polycondensation1
• Oxidation of carboranyl phosphine ligands2
• Synthesis of nickel-iron dithiolato hydrides3
• Ullmann reactions - homocoupling reactions4Co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers5Catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes6

REFERENCES