[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)

• Catalog No.: 328219
• CAS Number: 14647-23-5
• M. F.: C26H24Cl2NiP2
• M. W.: 528.015682

SYNONYMS

• Title: [1,2-双(二苯基膦)乙烷]二氯化镍(II)
• IUPAC name: [2-(diphenylphosphanyl)ethyl]diphenylphosphane; dichloronickel
• IUPAC Traditional name: diphos; nickel chloride
• Synonyms: [1,2-Bis(diphenylphosphino)ethane]nickel(II) chloride; Nickel 1,2-Bis(diphenylphosphino)ethane dichloride; 1,2-Ethylenebis(diphenylphosphine)nickel dichloride; dppeNiCl2

DATABASE IDS

• PubChem SID: 24859721
• MDL Number: MFCD00013313
• CAS Number: 14647-23-5

PROPERTIES

• Linear Formula: [(C6H5)2PCH2CH2P(C6H5)2]NiCl2
• Melting Point: 263-265 °C(lit.)
• GHS Signal Word: Danger
• GHS Hazard statements: H302-H312-H315-H319-H332-H334-H335-H350
• European Hazard Symbols: Toxic (T)
• Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
• GHS Precautionary statements: P201-P261-P280-P305 + P351 + P338-P308 + P313
• Risk Statements: 45-20/21/22-36/37/38-42/43
• Safety Statements: 53-22-26-36-45
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1, 5, 25 g in glass bottle
Application
Reactant involved in:
• Kumada catalyst-transfer polycondensation1
• Oxidation of carboranyl phosphine ligands2
• Synthesis of nickel-iron dithiolato hydrides3
• Ullmann reactions - homocoupling reactions4Co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers5Catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes6

Description (简体中文)

包装
1, 5, 25 g in glass bottle
Application
Reactant involved in:
• Kumada catalyst-transfer polycondensation1
• Oxidation of carboranyl phosphine ligands2
• Synthesis of nickel-iron dithiolato hydrides3
• Ullmann reactions - homocoupling reactions4Co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers5Catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes6