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Trimethylphosphine solution_Molecular_structure_CAS_594-09-2)
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Trimethylphosphine solution

Catalog No. 324108 Name Sigma Aldrich
CAS Number 594-09-2 Website http://www.sigmaaldrich.com
M. F. C3H9P Telephone 1-800-521-8956
M. W. 76.077321 Fax
Purity Email
Storage Chembase ID: 130013

SYNONYMS

Title
三甲基膦 溶液
IUPAC name
trimethylphosphane
IUPAC Traditional name
trimethylphosphine
Synonyms
Trimethylphosphorus
PMe3

DATABASE IDS

Beilstein Number 969138
PubChem SID 24859423
MDL Number MFCD00008510
CAS Number 594-09-2

PROPERTIES

Concentration 1.0 M in THF
Linear Formula (CH3)3P
Density 0.872 g/mL at 25 °C
Flash Point -30 °C
Flash Point -22 °F
Ligand For Mitsunobu Reaction
Ligand For Wittig Reaction
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H315-H319-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P261-P305 + P351 + P338
RID/ADR UN 1993 3/PG 2
Risk Statements 11-19-36/37
Safety Statements 16-26
Supplemental Hazard Statements May form explosive peroxides.
Hazard Class 3
UN Number 1993
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Application
Reagent used in Mitsunobu reaction; transformation of azides into carbamates, aziridines from azidoalcohols; iminophosphoranes and aza-Wittig reaction.
Packaging
100 mL in Sure/Seal™
Description (简体中文)
Application
Reagent used in Mitsunobu reaction; transformation of azides into carbamates, aziridines from azidoalcohols; iminophosphoranes and aza-Wittig reaction.
包装
100 mL in Sure/Seal™

REFERENCES