Tris[N,N-bis(trimethylsilyl)amide]samarium(III)

• Catalog No.: 547980
• CAS Number: 35789-01-6
• M. F.: C18H54N3Si6Sm
• M. W.: 631.51446
• Purity: 98%

SYNONYMS

• Title: 三[N,N-双(三甲基硅烷)胺]钐(III)
• IUPAC Traditional name: 2,2,6,6-tetramethyl-N,N,3,5-tetrakis(trimethylsilyl)-3,5-diaza-2,6-disila-4-samaraheptan-4-amine
• Synonyms: Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium; 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt

DATABASE IDS

• CAS Number: 35789-01-6
• MDL Number: MFCD03427097
• PubChem SID: 24879000

PROPERTIES

• Linear Formula: Sm(N(Si(CH3)3)2)3
• Purity: 98%
• Apperance: solid
• Flash Point: 2 °C
• Flash Point: 35.6 °F
• Melting Point: 93-106 °C(lit.)
• GHS Signal Word: Danger
• GHS Hazard statements: H228-H261-H314
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• GHS Precautionary statements: P210-P231 + P232-P280-P305 + P351 + P338-P310-P422
• RID/ADR: UN 3396 4.3/PG 2
• Risk Statements: 11-14/15-34
• Safety Statements: 7/8-16-26-36/37/39-43-45
• Supplemental Hazard Statements: Reacts violently with water.
• Hazard Class: 4.3
• UN Number: 3396
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1 g in glass bottle
Application
Reactant for synthesis of:
• Heterobimetallic samarium(III) complexes1
• Binuclear lanthanide complexes2Catalyst for:
• Coordination polymerization of renewable butyrolactone-based vinyl monomers3
• Intramolecular hydroamination of non-activated alkenes4
• Chiral functionalization of isoxazoles5
• Enantioselective hydroamination / cyclization6

Description (简体中文)

包装
1 g in glass bottle
Application
Reactant for synthesis of:
• Heterobimetallic samarium(III) complexes1
• Binuclear lanthanide complexes2Catalyst for:
• Coordination polymerization of renewable butyrolactone-based vinyl monomers3
• Intramolecular hydroamination of non-activated alkenes4
• Chiral functionalization of isoxazoles5
• Enantioselective hydroamination / cyclization6