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Bis(diethylamino)phenylphosphine

Catalog No. 554707 Name Sigma Aldrich
CAS Number 1636-14-2 Website http://www.sigmaaldrich.com
M. F. C14H25N2P Telephone 1-800-521-8956
M. W. 252.335461 Fax
Purity 97% Email
Storage Chembase ID: 144784

SYNONYMS

Title
双(二乙基氨基)苯膦
IUPAC name
[(diethylamino)(phenyl)phosphanyl]diethylamine
IUPAC Traditional name
[(diethylamino)(phenyl)phosphanyl]diethylamine
Synonyms
N,N,N′N′-Tetraethylphenylphosphonous diamide
NSC 244337
Phenylphosphonous tetraethyldiamide

DATABASE IDS

CAS Number 1636-14-2
PubChem SID 24879428
MDL Number MFCD01634466

PROPERTIES

Linear Formula C6H5P(N(CH2CH3)2)2
Purity 97%
Boiling Point 80 °C/0.005 mmHg(lit.)
Density 0.971 g/mL at 25 °C(lit.)
Flash Point 106 °C
Flash Point 222.8 °F
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves
German water hazard class 3

DETAILS

Description (English)
Packaging
5 g in glass bottle
Application

• Electron-withdrawing cocatalyst in rhodium catalyzed hydroformylation reactions1
• Ligand precatalyst for Heck coupling reactions2Reactant for:
• Preparation of palladium chiral P-N ligand complexes for regio- and stereo-selective dimerization reactions3
• Preparation of palladium tautomeric ferrocenylphosphinites as catalysts for Suzuki-Miyaura coupling4
• Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement of phosphinites and phosphites5
Description (简体中文)
包装
5 g in glass bottle
Application

• Electron-withdrawing cocatalyst in rhodium catalyzed hydroformylation reactions1
• Ligand precatalyst for Heck coupling reactions2Reactant for:
• Preparation of palladium chiral P-N ligand complexes for regio- and stereo-selective dimerization reactions3
• Preparation of palladium tautomeric ferrocenylphosphinites as catalysts for Suzuki-Miyaura coupling4
• Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement of phosphinites and phosphites5

REFERENCES