2,8,9-Triisopropyl-2,5,8,9-tetraaza-1-phosphabicyclo[3,3,3]undecane

• Catalog No.: 556955
• CAS Number: 175845-21-3
• M. F.: C15H33N4P
• M. W.: 300.423081

SYNONYMS

• Title: 2,8,9-三异丙基-2,5,8,9-四硫唑嘌呤-1-磷杂双环[3,3,3]十一烷
• IUPAC name: 2,8,9-tris(propan-2-yl)-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
• IUPAC Traditional name: 2,8,9-triisopropyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
• Synonyms: [2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane-2,8,9-tris(1-methylethyl)]; [2,5,8,9-四氮杂-1-磷杂双环[3.3.3]十一烷-2,8,9-三(1-甲基乙基)]

DATABASE IDS

• MDL Number: MFCD03701530
• PubChem SID: 24879596
• CAS Number: 175845-21-3

PROPERTIES

• Linear Formula: PN(CH(CH3)2)CH2CH2NCH2CH2N(CH(CH3)2)(CH2CH2N(CH(CH3)2))
• Density: 0.922 g/mL at 25 °C(lit.)
• Flash Point: 85 °C
• Flash Point: 185 °F
• Refractive Index: n20/D 1.4830(lit.)
• Personal Protective Equipment: Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
• German water hazard class: 3

DETAILS

Description (English)

Application
Catalyst used in the synthesis of β-hydroxyesters and α,β-unsaturated esters8
Base used in an attempt to produce higherly reactive no-carrier-added fluoride for labeling of radiopharmaceuticals1 and used in the synthesis of monomeric alumatranes2Deprotonation agent used to study the nucleophilic reactivities of benzenesulfonyl-substituted carbanions3Catalyst involved in:
• Synthesis of polymer-supported proazaphosphatranes for catalysis of amidation and transesterification reactions4
• Wadsworth-Emmons reactions5
• Mukaiyama aldol reactions6
• Synthesis of aryl alcohols via addition reactions7
Packaging
1, 5 g in glass bottle

Description (简体中文)

Application
作为催化剂用于 β-羟基酯和 α,β-不饱和酯的合成8
Base used in an attempt to produce higherly reactive no-carrier-added fluoride for labeling of radiopharmaceuticals1 and used in the synthesis of monomeric alumatranes2Deprotonation agent used to study the nucleophilic reactivities of benzenesulfonyl-substituted carbanions3Catalyst involved in:
• Synthesis of polymer-supported proazaphosphatranes for catalysis of amidation and transesterification reactions4
• Wadsworth-Emmons reactions5
• Mukaiyama aldol reactions6
• Synthesis of aryl alcohols via addition reactions7
包装
1, 5 g in glass bottle