Tris[N,N-bis(trimethylsilyl)amide]neodymium(III)

• Catalog No.: 547794
• CAS Number: 148274-47-9
• M. F.: C18H54N3NdSi6
• M. W.: 625.39446
• Purity: 97%

SYNONYMS

• Title: 三[N,N-双(三甲基硅烷)胺]钕(III)
• IUPAC name: 2,2,6,6-tetramethyl-N,N,3,5-tetrakis(trimethylsilyl)-3,5-diaza-2,6-disila-4-neodymaheptan-4-amine
• IUPAC Traditional name: 2,2,6,6-tetramethyl-N,N,3,5-tetrakis(trimethylsilyl)-3,5-diaza-2,6-disila-4-neodymaheptan-4-amine
• Synonyms: 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine neodymium(III) salt

DATABASE IDS

• MDL Number: MFCD03427089
• CAS Number: 148274-47-9
• PubChem SID: 24878980

PROPERTIES

• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• GHS Precautionary statements: P210-P231 + P232-P280-P305 + P351 + P338-P310-P422
• RID/ADR: UN 3396 4.3/PG 2
• Risk Statements: 11-14/15-34
• Safety Statements: 7/8-16-26-36/37/39-43-45
• Supplemental Hazard Statements: Reacts violently with water.
• Hazard Class: 4.3
• UN Number: 3396
• Packing Group: 2
• German water hazard class: 3
• GHS Signal Word: Danger
• GHS Hazard statements: H228-H261-H314
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• Linear Formula: Nd(N(Si(CH3)3)2)3
• Purity: 97%
• Apperance: solid
• Flash Point: 2 °C
• Flash Point: 35.6 °F
• Melting Point: 156-159 °C(lit.)

DETAILS

Description (English)

Packaging
1 g in glass bottle
Application
Reagent for synthesis of:
• Imidophosphinate complexes of lanthanides1
• Neodymium methoxides containing thienyl substituents2
• Phenylene-bridged binuclear organolanthanide complexes3
• Near-infrared photoluminescent neodymium(III) complexes4Reagent for:
• Rare-earth metal carboxylate-based catalysts5
• Regioselective C-H activation6

Description (简体中文)

包装
1 g in glass bottle
Application
Reagent for synthesis of:
• Imidophosphinate complexes of lanthanides1
• Neodymium methoxides containing thienyl substituents2
• Phenylene-bridged binuclear organolanthanide complexes3
• Near-infrared photoluminescent neodymium(III) complexes4Reagent for:
• Rare-earth metal carboxylate-based catalysts5
• Regioselective C-H activation6