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Dicyclohexyl(2-methylphenyl)phosphine_Molecular_structure_CAS_173593-25-4)
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Dicyclohexyl(2-methylphenyl)phosphine

Catalog No. 651885 Name Sigma Aldrich
CAS Number 173593-25-4 Website http://www.sigmaaldrich.com
M. F. C19H29P Telephone 1-800-521-8956
M. W. 288.407321 Fax
Purity 95% Email
Storage Chembase ID: 144614

SYNONYMS

Title
二环己基(2-甲基苯)膦
IUPAC name
dicyclohexyl(2-methylphenyl)phosphane
IUPAC Traditional name
dicyclohexyl(2-methylphenyl)phosphane
Synonyms
(o-Tolyl)dicyclohexylphosphine
(邻甲苯基)二环己基膦

DATABASE IDS

CAS Number 173593-25-4
MDL Number MFCD08276773
PubChem SID 24883863

PROPERTIES

Empirical Formula (Hill Notation) C19H29P
Purity 95%
Melting Point 90-93 °C
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335-H413
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Packaging
1 g in glass bottle
Application
Cocatalyst for:
• Nickel-catalyzed coupling reactions of alkenes, aldehydes, and silyl triflates1Catalyst for:
• Coupling of nonactivated and deactivated aryl chlorides with arylboronic acid2
• Preparation of (alkyl)(aryl)phosphines and triarylphosphines, as mediators of rhodium-catalyzed propene and hexene hydroformylation reactions3
• Ligand for PC bond cleavage during Heck vinylation of aryl halides with Bu acrylate in presence of palladium catalyst compounds4
Description (简体中文)
包装
1 g in glass bottle
Application
Cocatalyst for:
• Nickel-catalyzed coupling reactions of alkenes, aldehydes, and silyl triflates1Catalyst for:
• Coupling of nonactivated and deactivated aryl chlorides with arylboronic acid2
• Preparation of (alkyl)(aryl)phosphines and triarylphosphines, as mediators of rhodium-catalyzed propene and hexene hydroformylation reactions3
• Ligand for PC bond cleavage during Heck vinylation of aryl halides with Bu acrylate in presence of palladium catalyst compounds4

REFERENCES