(R)-(+)-2-Methyl-CBS-oxazaborolidine

• Catalog No.: 649317
• CAS Number: 112022-83-0
• M. F.: C18H20BNO
• M. W.: 277.1685
• Purity: ≥95%

SYNONYMS

• Title: (R)-(+)-2-甲基-CBS-噁唑硼烷
• IUPAC name: (3aR)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole
• IUPAC Traditional name: (3aR)-1-methyl-3,3-diphenyl-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole

DATABASE IDS

• CAS Number: 112022-83-0
• PubChem SID: 24883644
• MDL Number: MFCD00078440

PROPERTIES

• Empirical Formula (Hill Notation): C18H20BNO
• Purity: ≥95%
• Melting Point: 85-95 °C(lit.)
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1, 10 g in glass bottle
Application
CBS Catalysts for Asymmetric Reduction and Asymmetric Synthesis
The CBS (Corey-Bakshi-Shibata) oxazaborolidine catalyst has been used in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of α-hydroxy acids, α-amino acids, C2 symmetrical ferrocenyl diols, and propargyl alcohols.

Description (简体中文)

包装
1, 10 g in glass bottle
Application
CBS Catalysts for Asymmetric Reduction and Asymmetric Synthesis
CBS (Corey-Bakshi-Shibata) 噁唑硼烷催化剂已被用于前手性酮的非对称性还原。其他应用包括 α-羟基酸、α-氨基酸、C2 对称二茂铁二醇以及炔丙醇的对映选择性合成。