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2-(Trimethylsilyl)-2,3-pentadiene_Molecular_structure_CAS_77494-35-0)
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2-(Trimethylsilyl)-2,3-pentadiene

Catalog No. 720631 Name Sigma Aldrich
CAS Number 77494-35-0 Website http://www.sigmaaldrich.com
M. F. C8H16Si Telephone 1-800-521-8956
M. W. 140.29814 Fax
Purity Email
Storage Chembase ID: 143547

SYNONYMS

IUPAC name
trimethyl(penta-2,3-dien-2-yl)silane
IUPAC Traditional name
trimethyl(penta-2,3-dien-2-yl)silane
Synonyms
1,3-Dimethyl-1-(trimethylsilyl)allene

DATABASE IDS

CAS Number 77494-35-0
MDL Number MFCD17171289

PROPERTIES

Flash Point 15.8 °F
Refractive Index n20/D 1.444
Density 0.746 g/mL at 25 °C
Flash Point -9 °C
GHS Pictograms GHS02
GHS Signal Word Danger
GHS Hazard statements H225
European Hazard Symbols Flammable Flammable (F)
MSDS Link Download
GHS Precautionary statements P210
RID/ADR UN 1993 3/PG 2
Risk Statements 11
Safety Statements 16
Storage Temperature -20°C
Hazard Class 3
UN Number 1993
Packing Group 2
German water hazard class 3
Empirical Formula (Hill Notation) C8H16Si

DETAILS

Description (English)
Packaging
500 mg in glass bottle
Application
Reactant for:
• Oxidative cyclization with chlorine to give chloro- and acetoxybenziodoxaboroles and a self-assembled tetrameric macrocyclic structure1
• Preparation of allylic alcohols or enone derivatives using boronic acid as catalyst2Catalyst for:
• Preparation of acylsulfoximines via N-acylation of sulfoximines with aliphatic acids3
• Direct amide bond formation4
• Regioselective preparation of substituted triazole derivatives via dipolar cycloaddition of unsaturated carboxylic acids with azides5
Description (简体中文)
包装
500 mg in glass bottle
Application
Reactant for:
• Oxidative cyclization with chlorine to give chloro- and acetoxybenziodoxaboroles and a self-assembled tetrameric macrocyclic structure1
• Preparation of allylic alcohols or enone derivatives using boronic acid as catalyst2Catalyst for:
• Preparation of acylsulfoximines via N-acylation of sulfoximines with aliphatic acids3
• Direct amide bond formation4
• Regioselective preparation of substituted triazole derivatives via dipolar cycloaddition of unsaturated carboxylic acids with azides5

REFERENCES