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Bis(methyl-η5-cyclopentadienyl)dimethylhafnium_Molecular_structure_CAS_68193-43-1)
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Bis(methyl-η5-cyclopentadienyl)dimethylhafnium

Catalog No. 725501 Name Sigma Aldrich
CAS Number 68193-43-1 Website http://www.sigmaaldrich.com
M. F. C14H20Hf Telephone 1-800-521-8956
M. W. 366.7986 Fax
Purity Email
Storage Chembase ID: 143519

SYNONYMS

Title
二(甲基-η5-环戊二烯)二甲基铪
IUPAC name
bis(3-methylcyclopenta-2,4-dien-1-ide); dimethylhafniumbis(ylium)
IUPAC Traditional name
bis(3-methylcyclopenta-2,4-dien-1-ide); dimethylhafniumbis(ylium)
Synonyms
HfD-CO2
HFCMME

DATABASE IDS

CAS Number 68193-43-1
MDL Number MFCD16875684

PROPERTIES

Linear Formula Hf[C5H4(CH3)]2(CH3)2
Apperance white waxy solid
Boiling Point 80-120 °C/0.3-0.5 mmHg(lit.)
Density 1.60 g/mL±0.01 g/mL at 25 °C
Melting Point 60 °C(lit.)
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 24/25-26-36/37/39
German water hazard class 3

DETAILS

Description (English)
Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
Advanced precursor for atomic layer deposition of HfO2 thin films. Hafnium and zirconium oxides are leading candidates to replace silicion dioxide as the gate oxide in a variety of semiconductor and energy applications.1 Excellent properties of HfO2 and ZrO2 films make them especially attractive for gate oxide replacement and as potential insulating dielectrics for capacitive elements in memory devices such as DRAM.2
Features and Benefits
Compatible with a variety of oxidants in ALD growth processes across a wide temperature range exhibiting self limiting growth up to 400 °C. Precursor volatility and thermal stability properties enable easy materials transport from bubblers into conventional deposition tools.
General description
Atomic number of base material: 72 Hafnium
Packaging
10 g in ss cylinder
Packaged in stainless steel cylinders compatible with conventional deposition systems. Precursors may be used in liquid injection systems as dilute solutions and in combination with a variety of other sources to deposit mixed oxides.
Protocols & Applications
Precursors Packaged for Depositions Systems
Description (简体中文)
Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
Advanced precursor for atomic layer deposition of HfO2 thin films. Hafnium and zirconium oxides are leading candidates to replace silicion dioxide as the gate oxide in a variety of semiconductor and energy applications.1 Excellent properties of HfO2 and ZrO2 films make them especially attractive for gate oxide replacement and as potential insulating dielectrics for capacitive elements in memory devices such as DRAM.2
Features and Benefits
Compatible with a variety of oxidants in ALD growth processes across a wide temperature range exhibiting self limiting growth up to 400 °C. Precursor volatility and thermal stability properties enable easy materials transport from bubblers into conventional deposition tools.
General description
Atomic number of base material: 72 Hafnium
包装
10 g in ss cylinder
Packaged in stainless steel cylinders compatible with conventional deposition systems. Precursors may be used in liquid injection systems as dilute solutions and in combination with a variety of other sources to deposit mixed oxides.
Protocols & Applications
Precursors Packaged for Depositions Systems

REFERENCES